[3-Chloro-N′-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidato]methanol(methanolato)oxidovanadium(V)
In the title complex, [V(C18H11ClN2O2)(CH3O)O(CH3OH)], the VV ion is coordinated by a tridendate 3-chloro-N′-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidate ligand, one oxido ligand and by O atoms from a methanol and a methoxide ligand, forming a distorted octahedral geometry. The...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811032703 |
| Summary: | In the title complex, [V(C18H11ClN2O2)(CH3O)O(CH3OH)], the VV ion is coordinated by a tridendate 3-chloro-N′-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidate ligand, one oxido ligand and by O atoms from a methanol and a methoxide ligand, forming a distorted octahedral geometry. The dihedral angle between the benzene ring and the naphthylene ring system is 6.4 (3)°. The deviation of the VV ion from the plane defined by the three donor atoms of the tridentate ligand and the methoxy O atom towards the oxido O atom is 0.323 (2) Å. In the crystal, pairs of intermolecular O—H...N hydrogen bonds form centrosymmetric dimers. |
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| ISSN: | 1600-5368 |