Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)]
In the title complex, [Cu2V8O21(2,2′-bpy)2]n (bpy = bipyridine, C10H8N2), the asymmetric unit contains four independent V atoms briged by 11 O atoms, one of which lies on an inversion center, and a [Cu(2,2′-bpy)]2+ unit. Three V atoms in the polyoxoanion exhibit distorted...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-01-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809052118 |
id |
doaj-69281406667c498c8c02221e923fe9c4 |
---|---|
record_format |
Article |
spelling |
doaj-69281406667c498c8c02221e923fe9c42020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m32m3210.1107/S1600536809052118Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)]Hai-hui YuLi KongIn the title complex, [Cu2V8O21(2,2′-bpy)2]n (bpy = bipyridine, C10H8N2), the asymmetric unit contains four independent V atoms briged by 11 O atoms, one of which lies on an inversion center, and a [Cu(2,2′-bpy)]2+ unit. Three V atoms in the polyoxoanion exhibit distorted tetrahedral coordination geometries while the fourth V atom adopts a trigonal-bipyramidal geometry. The Cu atom adopts a square-pyramidal geometry being coordinated by two nitrogen donors of a 2,2′-bpy ligand, and three bridging O atoms which are linked with V atoms. The V8 polyoxoanion is connected to [Cu(2,2′-bpy)]2+ cations, resulting in a two-dimensional layer structure extending parallel to (010). C—H...O hydrogen bonding consolidates the structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809052118 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hai-hui Yu Li Kong |
spellingShingle |
Hai-hui Yu Li Kong Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] Acta Crystallographica Section E |
author_facet |
Hai-hui Yu Li Kong |
author_sort |
Hai-hui Yu |
title |
Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] |
title_short |
Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] |
title_full |
Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] |
title_fullStr |
Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] |
title_full_unstemmed |
Poly[bis(2,2′-bipyridine-κ2N,N′)heptadeca-μ-oxido-tetraoxidodicopper(II)divanadate(IV)hexavanadate(V)] |
title_sort |
poly[bis(2,2′-bipyridine-κ2n,n′)heptadeca-μ-oxido-tetraoxidodicopper(ii)divanadate(iv)hexavanadate(v)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-01-01 |
description |
In the title complex, [Cu2V8O21(2,2′-bpy)2]n (bpy = bipyridine, C10H8N2), the asymmetric unit contains four independent V atoms briged by 11 O atoms, one of which lies on an inversion center, and a [Cu(2,2′-bpy)]2+ unit. Three V atoms in the polyoxoanion exhibit distorted tetrahedral coordination geometries while the fourth V atom adopts a trigonal-bipyramidal geometry. The Cu atom adopts a square-pyramidal geometry being coordinated by two nitrogen donors of a 2,2′-bpy ligand, and three bridging O atoms which are linked with V atoms. The V8 polyoxoanion is connected to [Cu(2,2′-bpy)]2+ cations, resulting in a two-dimensional layer structure extending parallel to (010). C—H...O hydrogen bonding consolidates the structure. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809052118 |
work_keys_str_mv |
AT haihuiyu polybis22amp8242bipyridineamp9542nnamp8242heptadecaamp956oxidotetraoxidodicopperiidivanadateivhexavanadatev AT likong polybis22amp8242bipyridineamp9542nnamp8242heptadecaamp956oxidotetraoxidodicopperiidivanadateivhexavanadatev |
_version_ |
1725397857314275328 |