Thermodynamics for non-equilibrium pattern formation

The second entropy theory for non-equilibrium thermodynamics is used to show that the optimum structure or pattern of a time-dependent system corresponds to the maximum entropy. A formula for the total entropy of convective heat flow is derived. The Navier-Stokes equations in Boussinesq approximatio...

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Main Author: Phil Attard
Format: Article
Language:English
Published: AIP Publishing LLC 2011-09-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.3632033
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spelling doaj-69871ca503464744ae2273550c10082a2020-11-25T00:54:15ZengAIP Publishing LLCAIP Advances2158-32262011-09-0113032146032146-2010.1063/1.3632033046103ADVThermodynamics for non-equilibrium pattern formationPhil Attard02/52-56 Auburn st, Sutherland NSW 2232 AustraliaThe second entropy theory for non-equilibrium thermodynamics is used to show that the optimum structure or pattern of a time-dependent system corresponds to the maximum entropy. A formula for the total entropy of convective heat flow is derived. The Navier-Stokes equations in Boussinesq approximation for straight roll convection are solved by a Fourier expansion technique. Results for the velocity amplitude are in good agreement with previous computations and experimental measurements. For the spontaneous transitions between straight roll states reported in the literature, it is shown that the measured change in convective pattern wave length corresponds to an increase in the entropy.http://dx.doi.org/10.1063/1.3632033
collection DOAJ
language English
format Article
sources DOAJ
author Phil Attard
spellingShingle Phil Attard
Thermodynamics for non-equilibrium pattern formation
AIP Advances
author_facet Phil Attard
author_sort Phil Attard
title Thermodynamics for non-equilibrium pattern formation
title_short Thermodynamics for non-equilibrium pattern formation
title_full Thermodynamics for non-equilibrium pattern formation
title_fullStr Thermodynamics for non-equilibrium pattern formation
title_full_unstemmed Thermodynamics for non-equilibrium pattern formation
title_sort thermodynamics for non-equilibrium pattern formation
publisher AIP Publishing LLC
series AIP Advances
issn 2158-3226
publishDate 2011-09-01
description The second entropy theory for non-equilibrium thermodynamics is used to show that the optimum structure or pattern of a time-dependent system corresponds to the maximum entropy. A formula for the total entropy of convective heat flow is derived. The Navier-Stokes equations in Boussinesq approximation for straight roll convection are solved by a Fourier expansion technique. Results for the velocity amplitude are in good agreement with previous computations and experimental measurements. For the spontaneous transitions between straight roll states reported in the literature, it is shown that the measured change in convective pattern wave length corresponds to an increase in the entropy.
url http://dx.doi.org/10.1063/1.3632033
work_keys_str_mv AT philattard thermodynamicsfornonequilibriumpatternformation
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