New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin

New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin

The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction wi...

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Bibliographic Details
Main Authors: Adam Mondrzyk, Beate Mondrzik, Sabrina Gingter, Helmut Ritter
Format: Article
Language:English
Published: Beilstein-Institut 2012-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
copolymer
ß-cyclodextrin
enzymatic polymerization
4-ferrocenylphenol
polyphenol
4-tert-butylphenol
horseradish peroxidase
HRP oxidative coupling
inclusion complexes
polymer-analogous modification
Online Access:https://doi.org/10.3762/bjoc.8.238
Description
Summary:The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N3-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.
ISSN:1860-5397

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