New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin
The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction wi...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2012-12-01
|
Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.8.238 |
id |
doaj-6b21251d591741209d444a3cd6319e4a |
---|---|
record_format |
Article |
spelling |
doaj-6b21251d591741209d444a3cd6319e4a2021-02-02T03:26:45ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972012-12-01812118212310.3762/bjoc.8.2381860-5397-8-238New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrinAdam Mondrzyk0Beate Mondrzik1Sabrina Gingter2Helmut Ritter3Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N3-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.https://doi.org/10.3762/bjoc.8.238copolymerß-cyclodextrinenzymatic polymerization4-ferrocenylphenolpolyphenol4-tert-butylphenolhorseradish peroxidaseHRP oxidative couplinginclusion complexespolymer-analogous modification |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter |
spellingShingle |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin Beilstein Journal of Organic Chemistry copolymer ß-cyclodextrin enzymatic polymerization 4-ferrocenylphenol polyphenol 4-tert-butylphenol horseradish peroxidase HRP oxidative coupling inclusion complexes polymer-analogous modification |
author_facet |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter |
author_sort |
Adam Mondrzyk |
title |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
title_short |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
title_full |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
title_fullStr |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
title_full_unstemmed |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
title_sort |
new enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
publisher |
Beilstein-Institut |
series |
Beilstein Journal of Organic Chemistry |
issn |
1860-5397 |
publishDate |
2012-12-01 |
description |
The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N3-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement. |
topic |
copolymer ß-cyclodextrin enzymatic polymerization 4-ferrocenylphenol polyphenol 4-tert-butylphenol horseradish peroxidase HRP oxidative coupling inclusion complexes polymer-analogous modification |
url |
https://doi.org/10.3762/bjoc.8.238 |
work_keys_str_mv |
AT adammondrzyk newenzymaticallypolymerizedcopolymersfrom4tertbutylphenoland4ferrocenylphenolandtheirmodificationandinclusioncomplexeswithbcyclodextrin AT beatemondrzik newenzymaticallypolymerizedcopolymersfrom4tertbutylphenoland4ferrocenylphenolandtheirmodificationandinclusioncomplexeswithbcyclodextrin AT sabrinagingter newenzymaticallypolymerizedcopolymersfrom4tertbutylphenoland4ferrocenylphenolandtheirmodificationandinclusioncomplexeswithbcyclodextrin AT helmutritter newenzymaticallypolymerizedcopolymersfrom4tertbutylphenoland4ferrocenylphenolandtheirmodificationandinclusioncomplexeswithbcyclodextrin |
_version_ |
1724307786571972608 |