New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin
The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction wi...
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Beilstein-Institut
2012-12-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.8.238 |
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doaj-6b21251d591741209d444a3cd6319e4a2021-02-02T03:26:45ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972012-12-01812118212310.3762/bjoc.8.2381860-5397-8-238New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrinAdam Mondrzyk0Beate Mondrzik1Sabrina Gingter2Helmut Ritter3Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-811-5840The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N3-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.https://doi.org/10.3762/bjoc.8.238copolymerß-cyclodextrinenzymatic polymerization4-ferrocenylphenolpolyphenol4-tert-butylphenolhorseradish peroxidaseHRP oxidative couplinginclusion complexespolymer-analogous modification |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter |
| spellingShingle |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin Beilstein Journal of Organic Chemistry copolymer ß-cyclodextrin enzymatic polymerization 4-ferrocenylphenol polyphenol 4-tert-butylphenol horseradish peroxidase HRP oxidative coupling inclusion complexes polymer-analogous modification |
| author_facet |
Adam Mondrzyk Beate Mondrzik Sabrina Gingter Helmut Ritter |
| author_sort |
Adam Mondrzyk |
| title |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| title_short |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| title_full |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| title_fullStr |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| title_full_unstemmed |
New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| title_sort |
new enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin |
| publisher |
Beilstein-Institut |
| series |
Beilstein Journal of Organic Chemistry |
| issn |
1860-5397 |
| publishDate |
2012-12-01 |
| description |
The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H2O2 in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N3-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement. |
| topic |
copolymer ß-cyclodextrin enzymatic polymerization 4-ferrocenylphenol polyphenol 4-tert-butylphenol horseradish peroxidase HRP oxidative coupling inclusion complexes polymer-analogous modification |
| url |
https://doi.org/10.3762/bjoc.8.238 |
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