Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry

Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol est...

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Main Authors:	Jiří Kulhánek, Filip Bureš, Miroslav Ludwig
Format:	Article
Language:	English
Published:	Beilstein-Institut 2009-04-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	boronic acid donor/acceptor linker Sonogashira reaction property tuning push-pull Suzuki–Miyaura reaction
Online Access:	https://doi.org/10.3762/bjoc.5.11

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spelling	doaj-6b6b1a17028744eea0f7815e8f97dcb62021-02-02T07:54:14ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972009-04-01511110.3762/bjoc.5.111860-5397-5-11Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistryJiří Kulhánek0Filip Bureš1Miroslav Ludwig2Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicInstitute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicInstitute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicSimple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.https://doi.org/10.3762/bjoc.5.11boronic aciddonor/acceptorlinkerSonogashira reactionproperty tuningpush-pullSuzuki–Miyaura reaction
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jiří Kulhánek Filip Bureš Miroslav Ludwig
spellingShingle	Jiří Kulhánek Filip Bureš Miroslav Ludwig Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry Beilstein Journal of Organic Chemistry boronic acid donor/acceptor linker Sonogashira reaction property tuning push-pull Suzuki–Miyaura reaction
author_facet	Jiří Kulhánek Filip Bureš Miroslav Ludwig
author_sort	Jiří Kulhánek
title	Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_short	Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_full	Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_fullStr	Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_full_unstemmed	Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_sort	convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2009-04-01
description	Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.
topic	boronic acid donor/acceptor linker Sonogashira reaction property tuning push-pull Suzuki–Miyaura reaction
url	https://doi.org/10.3762/bjoc.5.11
work_keys_str_mv	AT jirikulhanek convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry AT filipbures convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry AT miroslavludwig convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry
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Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry

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