Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate

Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate

The asymmetric unit of the title compound, [Pd(C6H4NO2)4]·2H2O, consists of a quarter of a neutral PdIV complex and half of a solvent water molecule. In the complex, the PdIV ion is located on a fourfold inversion axis and eight-coordinated in a distorted dodecahedral environment by fou...

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Main Authors: Nam-Ho Kim, Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039270
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spelling doaj-6b8116031999480a93145ca006b38bc92020-11-25T00:50:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1274m127410.1107/S1600536809039270Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrateNam-Ho KimKwang HaThe asymmetric unit of the title compound, [Pd(C6H4NO2)4]·2H2O, consists of a quarter of a neutral PdIV complex and half of a solvent water molecule. In the complex, the PdIV ion is located on a fourfold inversion axis and eight-coordinated in a distorted dodecahedral environment by four N and four O atoms from four symmetry-related pyridine-2-carboxylate (pic) anionic ligands. In the crystal, the water molecule is involved in O—H...O hydrogen bonding, and weak intermolecular C—H...O hydrogen bonds occur. There are also intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.715 (3) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809039270
collection DOAJ
language English
format Article
sources DOAJ
author Nam-Ho Kim
Kwang Ha
spellingShingle Nam-Ho Kim
Kwang Ha
Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
Acta Crystallographica Section E
author_facet Nam-Ho Kim
Kwang Ha
author_sort Nam-Ho Kim
title Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
title_short Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
title_full Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
title_fullStr Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
title_full_unstemmed Tetrakis(pyridine-2-carboxylato-κ2N,O)palladium(IV) dihydrate
title_sort tetrakis(pyridine-2-carboxylato-κ2n,o)palladium(iv) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The asymmetric unit of the title compound, [Pd(C6H4NO2)4]·2H2O, consists of a quarter of a neutral PdIV complex and half of a solvent water molecule. In the complex, the PdIV ion is located on a fourfold inversion axis and eight-coordinated in a distorted dodecahedral environment by four N and four O atoms from four symmetry-related pyridine-2-carboxylate (pic) anionic ligands. In the crystal, the water molecule is involved in O—H...O hydrogen bonding, and weak intermolecular C—H...O hydrogen bonds occur. There are also intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.715 (3) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809039270
work_keys_str_mv AT namhokim tetrakispyridine2carboxylatoamp9542nopalladiumivdihydrate
AT kwangha tetrakispyridine2carboxylatoamp9542nopalladiumivdihydrate
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