SYNTHESIS AND CRYSTAL STRUCTURE OF A CU(II) COMPLEX AND ITS CATALYTIC ACTIVITY FOR THE OXIDATION OF BENZYL ALCOHOL

• Main Authors: JIE YIN, XI-SHI TAI, QIAN-QIN GUO
• Format: Article
• Language: English
• Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2018-09-01
• Series: Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
• Subjects: benzyl alcohol; 2-benzoylbenzoic acid; crystal structure; Cu(II) complex; oxidation; 1; 10-phenanthroline; synthesis
• Online Access: http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201803&vol=3&aid=4776
• ISSN: 1582-540X; 1582-540X

A Cu(II) complex, [CuL2(Phen)] (1) (HL = 2-benzoylbenzoic acid, Phen = 1,10-phenanthroline), has been synthesized and structurally characterized by elemental analysis and single-crystal X-ray diffraction. Structural analysis indicated that the Cu(II) complex (1) belongs to the monoclinic system with P21/c space group, and a = 18.955(4) Å, b = 8.3618(17) Å, c = 27.890(8) Å, β = 131.635(18)°, V = 3303.8(15) Å3, Dc = 1.396 g·cm-3, the final R = 0.0505, wR2 = 0.1154 with I≥2σ (I). In Cu(II) complex, both the COO- group of L ligand and Phen ligand adopt bidentate coordination mode. The Cu(II) center is six-coordinated by two N atoms of one Phen ligand and four O atoms of two different L ligands, forming a distorted octahedral coordination environment. The Cu(II) complex (1) molecules forms a 1D chain structure by π-π stacking effect of neighboring benzene rings, and the 1D chains further form a 3D network structure. The catalytic activity of [CuL2(Phen)] (1) for the oxidation of benzyl alcohol has been tested with O2 as the oxidant.