Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)

Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)

The title compound, [Zn(CH3)2(C15H11N3)], was synthesized by the addition of dimethylzinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The pentacoordinate ZnII atom, lying on a twofold rotation axis, displays...

Full description

Bibliographic Details
Main Authors: Tamila Shalumova, Joseph M. Tanski
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809040136
id doaj-6c4f7df683694ed2a1d375aa6d5e1451
record_format Article
spelling doaj-6c4f7df683694ed2a1d375aa6d5e14512020-11-24T21:28:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1325m132510.1107/S1600536809040136Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)Tamila ShalumovaJoseph M. TanskiThe title compound, [Zn(CH3)2(C15H11N3)], was synthesized by the addition of dimethylzinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The pentacoordinate ZnII atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions. http://scripts.iucr.org/cgi-bin/paper?S1600536809040136
collection DOAJ
language English
format Article
sources DOAJ
author Tamila Shalumova
Joseph M. Tanski
spellingShingle Tamila Shalumova
Joseph M. Tanski
Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
Acta Crystallographica Section E
author_facet Tamila Shalumova
Joseph M. Tanski
author_sort Tamila Shalumova
title Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
title_short Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
title_full Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
title_fullStr Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
title_full_unstemmed Dimethyl(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
title_sort dimethyl(2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The title compound, [Zn(CH3)2(C15H11N3)], was synthesized by the addition of dimethylzinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The pentacoordinate ZnII atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809040136
work_keys_str_mv AT tamilashalumova dimethyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242zincii
AT josephmtanski dimethyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242zincii
_version_ 1725968278591897600

Similar Items