Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide

Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide

In the title compound, C18H27N3OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexan...

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Bibliographic Details
Main Authors: Md. Azharul Arafath, Huey Chong Kwong, Farook Adam, Mohd. R. Razali
Format: Article
Language:English
Published: International Union of Crystallography 2018-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclohexylhydrazine
soft Lewis base
carbothioamide Schiff base
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018013129
Description
Summary:In the title compound, C18H27N3OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N—H...S hydrogen bonds, forming inversion dimers with an R22(8) ring motif.
ISSN:2056-9890

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