Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide

Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide

In the title compound, C18H27N3OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexan...

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Main Authors: Md. Azharul Arafath, Huey Chong Kwong, Farook Adam, Mohd. R. Razali
Format: Article
Language:English
Published: International Union of Crystallography 2018-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclohexylhydrazine
soft Lewis base
carbothioamide Schiff base
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018013129
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spelling doaj-6dbb57b4e5ea4d3a974638be26808e8d2020-11-25T02:29:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-10-0174101460146210.1107/S2056989018013129ld2145Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamideMd. Azharul Arafath0Huey Chong Kwong1Farook Adam2Mohd. R. Razali3Department of Chemistry, Shahjalal University of Science and Technology, Sylhet 3114, BangladeshSchool of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, MalaysiaIn the title compound, C18H27N3OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N—H...S hydrogen bonds, forming inversion dimers with an R22(8) ring motif.http://scripts.iucr.org/cgi-bin/paper?S2056989018013129crystal structurecyclohexylhydrazinesoft Lewis basecarbothioamide Schiff base
collection DOAJ
language English
format Article
sources DOAJ
author Md. Azharul Arafath
Huey Chong Kwong
Farook Adam
Mohd. R. Razali
spellingShingle Md. Azharul Arafath
Huey Chong Kwong
Farook Adam
Mohd. R. Razali
Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
cyclohexylhydrazine
soft Lewis base
carbothioamide Schiff base
author_facet Md. Azharul Arafath
Huey Chong Kwong
Farook Adam
Mohd. R. Razali
author_sort Md. Azharul Arafath
title Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
title_short Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
title_full Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
title_fullStr Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
title_full_unstemmed Crystal structure of (E)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-N-cyclohexylhydrazine-1-carbothioamide
title_sort crystal structure of (e)-2-[3-(tert-butyl)-2-hydroxybenzylidene]-n-cyclohexylhydrazine-1-carbothioamide
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2018-10-01
description In the title compound, C18H27N3OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N—H...S hydrogen bonds, forming inversion dimers with an R22(8) ring motif.
topic crystal structure
cyclohexylhydrazine
soft Lewis base
carbothioamide Schiff base
url http://scripts.iucr.org/cgi-bin/paper?S2056989018013129
work_keys_str_mv AT mdazharularafath crystalstructureofe23tertbutyl2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
AT hueychongkwong crystalstructureofe23tertbutyl2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
AT farookadam crystalstructureofe23tertbutyl2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
AT mohdrrazali crystalstructureofe23tertbutyl2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
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