Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System

Refractory high entropy alloys (HEA) are promising materials for high temperature applications. This work presents investigations of the room temperature tensile mechanical properties of selected 3 and 4 elements medium entropy alloys (MEA) derived from the HfNbTaTiZr system. Tensile testing was com...

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Main Authors: Jiří Zýka, Jaroslav Málek, Jaroslav Veselý, František Lukáč, Jakub Čížek, Jan Kuriplach, Oksana Melikhova
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/21/2/114
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spelling doaj-6e03dd68be0641ae80297a79e024277f2020-11-24T21:58:28ZengMDPI AGEntropy1099-43002019-01-0121211410.3390/e21020114e21020114Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr SystemJiří Zýka0Jaroslav Málek1Jaroslav Veselý2František Lukáč3Jakub Čížek4Jan Kuriplach5Oksana Melikhova6UJP PRAHA a.s., Nad Kamínkou 1345, 156 10 Praha 5—Zbraslav, Czech RepublicUJP PRAHA a.s., Nad Kamínkou 1345, 156 10 Praha 5—Zbraslav, Czech RepublicUJP PRAHA a.s., Nad Kamínkou 1345, 156 10 Praha 5—Zbraslav, Czech RepublicDepartment of Materials Engineering, Institute of Plasma Physics CAS, Za Slovankou 1782, 1820 Praha 8, Czech RepublicFaculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Praha 8, Czech RepublicFaculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Praha 8, Czech RepublicFaculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Praha 8, Czech RepublicRefractory high entropy alloys (HEA) are promising materials for high temperature applications. This work presents investigations of the room temperature tensile mechanical properties of selected 3 and 4 elements medium entropy alloys (MEA) derived from the HfNbTaTiZr system. Tensile testing was combined with fractographic and microstructure analysis, using scanning electron microscope (SEM), wavelength dispersive spectroscope (WDS) and X-Ray powder diffraction (XRD). The 5 element HEA alloy HfNbTaTiZr exhibits the best combination of strength and elongation while 4 and 3 element MEAs have lower strength. Some of them are ductile, some of them brittle, depending on microstructure. Simultaneous presence of Ta and Zr in the alloy resulted in a significant reduction of ductility caused by reduction of the BCC phase content. Precipitation of Ta rich particles on grain boundaries reduces further the maximum elongation to failure down to zero values.https://www.mdpi.com/1099-4300/21/2/114refractory high entropy alloysmedium entropy alloys, mechanical propertiesmicrostructure
collection DOAJ
language English
format Article
sources DOAJ
author Jiří Zýka
Jaroslav Málek
Jaroslav Veselý
František Lukáč
Jakub Čížek
Jan Kuriplach
Oksana Melikhova
spellingShingle Jiří Zýka
Jaroslav Málek
Jaroslav Veselý
František Lukáč
Jakub Čížek
Jan Kuriplach
Oksana Melikhova
Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
Entropy
refractory high entropy alloys
medium entropy alloys, mechanical properties
microstructure
author_facet Jiří Zýka
Jaroslav Málek
Jaroslav Veselý
František Lukáč
Jakub Čížek
Jan Kuriplach
Oksana Melikhova
author_sort Jiří Zýka
title Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
title_short Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
title_full Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
title_fullStr Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
title_full_unstemmed Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System
title_sort microstructure and room temperature mechanical properties of different 3 and 4 element medium entropy alloys from hfnbtatizr system
publisher MDPI AG
series Entropy
issn 1099-4300
publishDate 2019-01-01
description Refractory high entropy alloys (HEA) are promising materials for high temperature applications. This work presents investigations of the room temperature tensile mechanical properties of selected 3 and 4 elements medium entropy alloys (MEA) derived from the HfNbTaTiZr system. Tensile testing was combined with fractographic and microstructure analysis, using scanning electron microscope (SEM), wavelength dispersive spectroscope (WDS) and X-Ray powder diffraction (XRD). The 5 element HEA alloy HfNbTaTiZr exhibits the best combination of strength and elongation while 4 and 3 element MEAs have lower strength. Some of them are ductile, some of them brittle, depending on microstructure. Simultaneous presence of Ta and Zr in the alloy resulted in a significant reduction of ductility caused by reduction of the BCC phase content. Precipitation of Ta rich particles on grain boundaries reduces further the maximum elongation to failure down to zero values.
topic refractory high entropy alloys
medium entropy alloys, mechanical properties
microstructure
url https://www.mdpi.com/1099-4300/21/2/114
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