Membrane Functionalization with Hyperbranched Polymers
Polymer membranes have been modified with hyperbranched polymers with the aim to generate a high density of hydrophilic functional groups at the membrane surface. For this purpose hyperbranched polymers containing amino, alcohol, and carboxylic acid end groups were used for membrane modification, re...
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doaj-6eb5159f45ea441a961d103088abd4c02020-11-24T22:29:54ZengMDPI AGMaterials1996-19442016-08-019870610.3390/ma9080706ma9080706Membrane Functionalization with Hyperbranched PolymersAgnes Schulze0Marco Went1Andrea Prager2Leibniz Institute of Surface Functionalization, Permoserstr. 15, Leipzig D-04318, GermanyLeibniz Institute of Surface Functionalization, Permoserstr. 15, Leipzig D-04318, GermanyLeibniz Institute of Surface Functionalization, Permoserstr. 15, Leipzig D-04318, GermanyPolymer membranes have been modified with hyperbranched polymers with the aim to generate a high density of hydrophilic functional groups at the membrane surface. For this purpose hyperbranched polymers containing amino, alcohol, and carboxylic acid end groups were used for membrane modification, respectively. Thus, surface potential and charges were changed significantly to result in attractive or repulsive interactions towards three different proteins (albumin, lysozyme, myoglobin) that were used to indicate membrane fouling properties. Our studies demonstrated that hydrophilization alone is not effective for avoiding membrane fouling when charged proteins are present. In contrast, electrostatic repulsion seems to be a general key factor.http://www.mdpi.com/1996-1944/9/8/706polymer membraneshyperbranched polymerssurface functionalizationzeta potentialprotein adsorption |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Agnes Schulze Marco Went Andrea Prager |
spellingShingle |
Agnes Schulze Marco Went Andrea Prager Membrane Functionalization with Hyperbranched Polymers Materials polymer membranes hyperbranched polymers surface functionalization zeta potential protein adsorption |
author_facet |
Agnes Schulze Marco Went Andrea Prager |
author_sort |
Agnes Schulze |
title |
Membrane Functionalization with Hyperbranched Polymers |
title_short |
Membrane Functionalization with Hyperbranched Polymers |
title_full |
Membrane Functionalization with Hyperbranched Polymers |
title_fullStr |
Membrane Functionalization with Hyperbranched Polymers |
title_full_unstemmed |
Membrane Functionalization with Hyperbranched Polymers |
title_sort |
membrane functionalization with hyperbranched polymers |
publisher |
MDPI AG |
series |
Materials |
issn |
1996-1944 |
publishDate |
2016-08-01 |
description |
Polymer membranes have been modified with hyperbranched polymers with the aim to generate a high density of hydrophilic functional groups at the membrane surface. For this purpose hyperbranched polymers containing amino, alcohol, and carboxylic acid end groups were used for membrane modification, respectively. Thus, surface potential and charges were changed significantly to result in attractive or repulsive interactions towards three different proteins (albumin, lysozyme, myoglobin) that were used to indicate membrane fouling properties. Our studies demonstrated that hydrophilization alone is not effective for avoiding membrane fouling when charged proteins are present. In contrast, electrostatic repulsion seems to be a general key factor. |
topic |
polymer membranes hyperbranched polymers surface functionalization zeta potential protein adsorption |
url |
http://www.mdpi.com/1996-1944/9/8/706 |
work_keys_str_mv |
AT agnesschulze membranefunctionalizationwithhyperbranchedpolymers AT marcowent membranefunctionalizationwithhyperbranchedpolymers AT andreaprager membranefunctionalizationwithhyperbranchedpolymers |
_version_ |
1725742909512220672 |