Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base

In this article, we have introduced an intermediate benzyl carbocation (formed as a result of photoionization) which serves as precursor for the synthesis of Schiff’s base. Lifetimes of many carbocations were determined from our laboratory. During the determination of the lifetimes, our endeavor was...

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Main Authors:	R. Sanjeev, V. Jagannadham, R. V. Vrath, R. Ravi
Format:	Article
Language:	English
Published:	Chemical Society of Ethiopia 2014-05-01
Series:	Bulletin of the Chemical Society of Ethiopia
Subjects:	Carbocation Selectivity Intermediates Solvolysis Photoionization and Iminodiazonium ion
Online Access:	http://www.ajol.info/index.php/bcse/article/view/103691

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spelling	doaj-6ecd63a5699a4d57933b36b5b8522c912020-11-25T00:20:14ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2014-05-0128129530010.4314/bcse.v28i2.13Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s baseR. SanjeevV. JagannadhamR. V. VrathR. RaviIn this article, we have introduced an intermediate benzyl carbocation (formed as a result of photoionization) which serves as precursor for the synthesis of Schiff’s base. Lifetimes of many carbocations were determined from our laboratory. During the determination of the lifetimes, our endeavor was to obtain a carbocation with high selectivity, s = knu/kH2O. The selectivity is the ratio of the rate constant of the reaction of carbocation with an externally added nucleophile, (nu, aniline) to that of the rate constant of the water. Our intention was to obtain a carbocation with high selectivity, so that one can pave a path for the synthesis of Schiff’s base by the reaction of the carbocation intermediate with aniline. DOI: http://dx.doi.org/10.4314/bcse.v28i2.13http://www.ajol.info/index.php/bcse/article/view/103691CarbocationSelectivityIntermediatesSolvolysisPhotoionization and Iminodiazonium ion
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	R. Sanjeev V. Jagannadham R. V. Vrath R. Ravi
spellingShingle	R. Sanjeev V. Jagannadham R. V. Vrath R. Ravi Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base Bulletin of the Chemical Society of Ethiopia Carbocation Selectivity Intermediates Solvolysis Photoionization and Iminodiazonium ion
author_facet	R. Sanjeev V. Jagannadham R. V. Vrath R. Ravi
author_sort	R. Sanjeev
title	Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base
title_short	Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base
title_full	Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base
title_fullStr	Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base
title_full_unstemmed	Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base
title_sort	intermediate obtained from photoionization, serving as precursor for the synthesis of schiff’s base
publisher	Chemical Society of Ethiopia
series	Bulletin of the Chemical Society of Ethiopia
issn	1011-3924 1726-801X
publishDate	2014-05-01
description	In this article, we have introduced an intermediate benzyl carbocation (formed as a result of photoionization) which serves as precursor for the synthesis of Schiff’s base. Lifetimes of many carbocations were determined from our laboratory. During the determination of the lifetimes, our endeavor was to obtain a carbocation with high selectivity, s = knu/kH2O. The selectivity is the ratio of the rate constant of the reaction of carbocation with an externally added nucleophile, (nu, aniline) to that of the rate constant of the water. Our intention was to obtain a carbocation with high selectivity, so that one can pave a path for the synthesis of Schiff’s base by the reaction of the carbocation intermediate with aniline. DOI: http://dx.doi.org/10.4314/bcse.v28i2.13
topic	Carbocation Selectivity Intermediates Solvolysis Photoionization and Iminodiazonium ion
url	http://www.ajol.info/index.php/bcse/article/view/103691
work_keys_str_mv	AT rsanjeev intermediateobtainedfromphotoionizationservingasprecursorforthesynthesisofschiffsbase AT vjagannadham intermediateobtainedfromphotoionizationservingasprecursorforthesynthesisofschiffsbase AT rvvrath intermediateobtainedfromphotoionizationservingasprecursorforthesynthesisofschiffsbase AT rravi intermediateobtainedfromphotoionizationservingasprecursorforthesynthesisofschiffsbase
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Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base

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