Isolation of a Cyclic (Alkyl)(amino)germylene
A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO...
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doaj-6fb3bf52ecb149a88d4f42396863e8832020-11-25T00:36:56ZengMDPI AGMolecules1420-30492016-07-0121899010.3390/molecules21080990molecules21080990Isolation of a Cyclic (Alkyl)(amino)germyleneLiliang Wang0Yi Shan Lim1Yongxin Li2Rakesh Ganguly3Rei Kinjo4Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeNTU-CBC Crystallography Facility, Nanyang Technological University Nanyang Link 21, Singapore 637371, SingaporeNTU-CBC Crystallography Facility, Nanyang Technological University Nanyang Link 21, Singapore 637371, SingaporeDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeA 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.http://www.mdpi.com/1420-3049/21/8/990germylenelow-valent germaniumsulfurTEMPOnitrous oxide |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo |
spellingShingle |
Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo Isolation of a Cyclic (Alkyl)(amino)germylene Molecules germylene low-valent germanium sulfur TEMPO nitrous oxide |
author_facet |
Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo |
author_sort |
Liliang Wang |
title |
Isolation of a Cyclic (Alkyl)(amino)germylene |
title_short |
Isolation of a Cyclic (Alkyl)(amino)germylene |
title_full |
Isolation of a Cyclic (Alkyl)(amino)germylene |
title_fullStr |
Isolation of a Cyclic (Alkyl)(amino)germylene |
title_full_unstemmed |
Isolation of a Cyclic (Alkyl)(amino)germylene |
title_sort |
isolation of a cyclic (alkyl)(amino)germylene |
publisher |
MDPI AG |
series |
Molecules |
issn |
1420-3049 |
publishDate |
2016-07-01 |
description |
A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. |
topic |
germylene low-valent germanium sulfur TEMPO nitrous oxide |
url |
http://www.mdpi.com/1420-3049/21/8/990 |
work_keys_str_mv |
AT liliangwang isolationofacyclicalkylaminogermylene AT yishanlim isolationofacyclicalkylaminogermylene AT yongxinli isolationofacyclicalkylaminogermylene AT rakeshganguly isolationofacyclicalkylaminogermylene AT reikinjo isolationofacyclicalkylaminogermylene |
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