Isolation of a Cyclic (Alkyl)(amino)germylene

A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO...

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Main Authors:	Liliang Wang, Yi Shan Lim, Yongxin Li, Rakesh Ganguly, Rei Kinjo
Format:	Article
Language:	English
Published:	MDPI AG 2016-07-01
Series:	Molecules
Subjects:	germylene low-valent germanium sulfur TEMPO nitrous oxide
Online Access:	http://www.mdpi.com/1420-3049/21/8/990

id	doaj-6fb3bf52ecb149a88d4f42396863e883
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spelling	doaj-6fb3bf52ecb149a88d4f42396863e8832020-11-25T00:36:56ZengMDPI AGMolecules1420-30492016-07-0121899010.3390/molecules21080990molecules21080990Isolation of a Cyclic (Alkyl)(amino)germyleneLiliang Wang0Yi Shan Lim1Yongxin Li2Rakesh Ganguly3Rei Kinjo4Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeNTU-CBC Crystallography Facility, Nanyang Technological University Nanyang Link 21, Singapore 637371, SingaporeNTU-CBC Crystallography Facility, Nanyang Technological University Nanyang Link 21, Singapore 637371, SingaporeDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, SingaporeA 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.http://www.mdpi.com/1420-3049/21/8/990germylenelow-valent germaniumsulfurTEMPOnitrous oxide
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo
spellingShingle	Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo Isolation of a Cyclic (Alkyl)(amino)germylene Molecules germylene low-valent germanium sulfur TEMPO nitrous oxide
author_facet	Liliang Wang Yi Shan Lim Yongxin Li Rakesh Ganguly Rei Kinjo
author_sort	Liliang Wang
title	Isolation of a Cyclic (Alkyl)(amino)germylene
title_short	Isolation of a Cyclic (Alkyl)(amino)germylene
title_full	Isolation of a Cyclic (Alkyl)(amino)germylene
title_fullStr	Isolation of a Cyclic (Alkyl)(amino)germylene
title_full_unstemmed	Isolation of a Cyclic (Alkyl)(amino)germylene
title_sort	isolation of a cyclic (alkyl)(amino)germylene
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2016-07-01
description	A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.
topic	germylene low-valent germanium sulfur TEMPO nitrous oxide
url	http://www.mdpi.com/1420-3049/21/8/990
work_keys_str_mv	AT liliangwang isolationofacyclicalkylaminogermylene AT yishanlim isolationofacyclicalkylaminogermylene AT yongxinli isolationofacyclicalkylaminogermylene AT rakeshganguly isolationofacyclicalkylaminogermylene AT reikinjo isolationofacyclicalkylaminogermylene
_version_	1725303454035869696

Isolation of a Cyclic (Alkyl)(amino)germylene

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