Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance

At present, nanomaterials with high-quality photoelectric properties are urgently needed to be used in the manufacture of solar cells. In this study, the hydrothermal synthesis method was first used to grow ZnO nanorod arrays, and then a layer of WO<sub>3</sub> thin film with controllabl...

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Main Authors: Yan Xu, Qin Cao, Zao Yi, Pinghui Wu, Shuangshuang Cai
Format: Article
Language:English
Published: IEEE 2020-01-01
Series:IEEE Access
Subjects:
Online Access:https://ieeexplore.ieee.org/document/9204702/
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spelling doaj-6fbc14b76d7e450db35d95ba270c1a232021-03-30T03:59:41ZengIEEEIEEE Access2169-35362020-01-01817135017135810.1109/ACCESS.2020.30248279204702Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric PerformanceYan Xu0Qin Cao1Zao Yi2https://orcid.org/0000-0002-7019-7481Pinghui Wu3https://orcid.org/0000-0002-3980-4319Shuangshuang Cai4School of Science, Huzhou University, Huzhou, ChinaJoint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology, Mianyang, ChinaJoint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology, Mianyang, ChinaFujian Provincial Key Laboratory for Advanced Micro-Nano Photonics Technology and Devices, Research Center for Photonic Technology, Quanzhou Normal University, Quanzhou, ChinaSchool of Biomedical Engineering, Wenzhou Medical University, Wenzhou, ChinaAt present, nanomaterials with high-quality photoelectric properties are urgently needed to be used in the manufacture of solar cells. In this study, the hydrothermal synthesis method was first used to grow ZnO nanorod arrays, and then a layer of WO<sub>3</sub> thin film with controllable thickness was prepared on ZnO nanorod arrays by magnetron sputtering, forming a series of WO<sub>3</sub>@ZnO nanocomposite heterojunction. We found that the value of the photocurrent of the prepared nanocomposite samples is nearly 30 times higher than WO<sub>3</sub> films under illumination, and it is more stable. The results show that this controllable microstructure can further modify the surface properties of ZnO nanorods, and possess the high visible absorption and photoelectric conversion efficiency. By controlling the thickness of the WO<sub>3</sub> film, the band can be regulated and ultimately optimized the photoelectrochemical properties of the composite structure.https://ieeexplore.ieee.org/document/9204702/WO₃@ZnO nano-heterostructureshydrothermal methodmagnetron sputteringphotoelectricband regulation
collection DOAJ
language English
format Article
sources DOAJ
author Yan Xu
Qin Cao
Zao Yi
Pinghui Wu
Shuangshuang Cai
spellingShingle Yan Xu
Qin Cao
Zao Yi
Pinghui Wu
Shuangshuang Cai
Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
IEEE Access
WO₃@ZnO nano-heterostructures
hydrothermal method
magnetron sputtering
photoelectric
band regulation
author_facet Yan Xu
Qin Cao
Zao Yi
Pinghui Wu
Shuangshuang Cai
author_sort Yan Xu
title Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
title_short Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
title_full Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
title_fullStr Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
title_full_unstemmed Adjusting the Energy Bands of WO<sub>3</sub>&#x0040;ZnO Nanocomposite Heterojunction Through the Combination of WO<sub>3</sub> Thin Film to Improve its Photoelectric Performance
title_sort adjusting the energy bands of wo<sub>3</sub>&#x0040;zno nanocomposite heterojunction through the combination of wo<sub>3</sub> thin film to improve its photoelectric performance
publisher IEEE
series IEEE Access
issn 2169-3536
publishDate 2020-01-01
description At present, nanomaterials with high-quality photoelectric properties are urgently needed to be used in the manufacture of solar cells. In this study, the hydrothermal synthesis method was first used to grow ZnO nanorod arrays, and then a layer of WO<sub>3</sub> thin film with controllable thickness was prepared on ZnO nanorod arrays by magnetron sputtering, forming a series of WO<sub>3</sub>@ZnO nanocomposite heterojunction. We found that the value of the photocurrent of the prepared nanocomposite samples is nearly 30 times higher than WO<sub>3</sub> films under illumination, and it is more stable. The results show that this controllable microstructure can further modify the surface properties of ZnO nanorods, and possess the high visible absorption and photoelectric conversion efficiency. By controlling the thickness of the WO<sub>3</sub> film, the band can be regulated and ultimately optimized the photoelectrochemical properties of the composite structure.
topic WO₃@ZnO nano-heterostructures
hydrothermal method
magnetron sputtering
photoelectric
band regulation
url https://ieeexplore.ieee.org/document/9204702/
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