Sulfenamide-enabled ortho thiolation of aryl iodides via palladium/norbornene cooperative catalysis

Poly-substituted aromatic sulfur compounds are part of many pharmaceuticals, agrochemicals and organic materials. Here, the authors developed a sulfenamide-enabled ortho-thiolation of aryl iodides via Pd/norbornene cooperative catalysis for the preparation of polysubstituted aromatic sulfur compound...

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Bibliographic Details
Main Authors: Renhe Li, Yun Zhou, Ki-Young Yoon, Zhe Dong, Guangbin Dong
Format: Article
Language:English
Published: Nature Publishing Group 2019-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-11398-0
Description
Summary:Poly-substituted aromatic sulfur compounds are part of many pharmaceuticals, agrochemicals and organic materials. Here, the authors developed a sulfenamide-enabled ortho-thiolation of aryl iodides via Pd/norbornene cooperative catalysis for the preparation of polysubstituted aromatic sulfur compounds.
ISSN:2041-1723