Impact of cyclodextrins on the behavior of amphiphilic ligands in aqueous organometallic catalysis

Impact of cyclodextrins on the behavior of amphiphilic ligands in aqueous organometallic catalysis

In this study, we showed that the addition of randomly modified β-cyclodextrin (RAME-β-CD) in aqueous medium could have a beneficial impact on the catalytic performances of phosphane-based aggregates in the Pd-catalyzed cleavage of allyl carbonates (Tsuji–Trost reaction). The RAME-β-CD/phosphane sup...

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Bibliographic Details
Main Authors: Hervé Bricout, Estelle Léonard, Christophe Len, David Landy, Frédéric Hapiot, Eric Monflier
Format: Article
Language:English
Published: Beilstein-Institut 2012-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
amphiphilic phosphanes
biphasic system
cyclodextrins
micelles
Online Access:https://doi.org/10.3762/bjoc.8.167

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