Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)

Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)

In the title complex, [Cu(C14H13N2O2)2], the CuII ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN2O2] coordination geometry, with the CuII ion coordinated by two 2-methoxy-6-(3-pyridylmethyliminomethyl)phenolate (Schiff base) ligands. The ary...

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Main Authors: Xiaodan Chen, Yu Sun, Qingzhao Yao, Huaihong Zhang, Qing Liang
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809052349
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spelling doaj-70c333dc8dc143bb9ec982f8c77ef7bc2020-11-25T00:50:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m39m3910.1107/S1600536809052349Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)Xiaodan ChenYu SunQingzhao YaoHuaihong ZhangQing LiangIn the title complex, [Cu(C14H13N2O2)2], the CuII ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN2O2] coordination geometry, with the CuII ion coordinated by two 2-methoxy-6-(3-pyridylmethyliminomethyl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component http://scripts.iucr.org/cgi-bin/paper?S1600536809052349
collection DOAJ
language English
format Article
sources DOAJ
author Xiaodan Chen
Yu Sun
Qingzhao Yao
Huaihong Zhang
Qing Liang
spellingShingle Xiaodan Chen
Yu Sun
Qingzhao Yao
Huaihong Zhang
Qing Liang
Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
Acta Crystallographica Section E
author_facet Xiaodan Chen
Yu Sun
Qingzhao Yao
Huaihong Zhang
Qing Liang
author_sort Xiaodan Chen
title Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
title_short Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
title_full Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
title_fullStr Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
title_full_unstemmed Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)
title_sort bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2n,o]copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title complex, [Cu(C14H13N2O2)2], the CuII ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN2O2] coordination geometry, with the CuII ion coordinated by two 2-methoxy-6-(3-pyridylmethyliminomethyl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component
url http://scripts.iucr.org/cgi-bin/paper?S1600536809052349
work_keys_str_mv AT xiaodanchen bis2methoxy63pyridylmethyliminomethylphenolatoamp9542nocopperii
AT yusun bis2methoxy63pyridylmethyliminomethylphenolatoamp9542nocopperii
AT qingzhaoyao bis2methoxy63pyridylmethyliminomethylphenolatoamp9542nocopperii
AT huaihongzhang bis2methoxy63pyridylmethyliminomethylphenolatoamp9542nocopperii
AT qingliang bis2methoxy63pyridylmethyliminomethylphenolatoamp9542nocopperii
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