Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine
We herein reported the syntheses, crystal structures, and magnetic properties of a two-dimensional coordination polymer {[CoII(TPT)2/3(H2O)4][CH3COO]2·(H2O)4}n (1) and a chain compound {[CoII(TPT)2(CHOO)2(H2O)2]}n (2) based on the 2,4,6-Tris(4-pyridyl)-1,3,5-triazine (TPT) ligand. Structure analyses...
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doaj-7226391c7cf1495ab5f42f019ac94d002020-11-24T21:48:27ZengMDPI AGInorganics2304-67402017-12-01549010.3390/inorganics5040090inorganics5040090Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazineDong Shao0Le Shi1Hai-Yan Wei2Xin-Yi Wang3State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, ChinaState Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, ChinaJiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, ChinaState Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, ChinaWe herein reported the syntheses, crystal structures, and magnetic properties of a two-dimensional coordination polymer {[CoII(TPT)2/3(H2O)4][CH3COO]2·(H2O)4}n (1) and a chain compound {[CoII(TPT)2(CHOO)2(H2O)2]}n (2) based on the 2,4,6-Tris(4-pyridyl)-1,3,5-triazine (TPT) ligand. Structure analyses showed that complex 1 had a cationic hexagonal framework structure, while 2 was a neutral zig-zag chain structure with different distorted octahedral coordination environments. Magnetic measurements revealed that both complexes exhibit large easy-plane magnetic anisotropy with the zero-field splitting parameter D = 47.7 and 62.1 cm−1 for 1 and 2, respectively. This magnetic anisotropy leads to the field-induced slow magnetic relaxation behaviour. However, their magnetic dynamics are quite different; while complex 1 experienced a dominating thermally activated Orbach relaxation at the whole measured temperature region, 2 exhibited multiple relaxation pathways involving direct, Raman, and quantum tunneling (QTM) processes at low temperatures and Orbach relaxation at high temperatures. The present complexes enlarge the family of framework-based single-ion magnets (SIMs) and highlight the significance of the structural dimensionality to the final magnetic properties.https://www.mdpi.com/2304-6740/5/4/90single-ion magnetcobalt(II)magnetic anisotropycoordination polymers |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Dong Shao Le Shi Hai-Yan Wei Xin-Yi Wang |
spellingShingle |
Dong Shao Le Shi Hai-Yan Wei Xin-Yi Wang Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine Inorganics single-ion magnet cobalt(II) magnetic anisotropy coordination polymers |
author_facet |
Dong Shao Le Shi Hai-Yan Wei Xin-Yi Wang |
author_sort |
Dong Shao |
title |
Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine |
title_short |
Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine |
title_full |
Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine |
title_fullStr |
Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine |
title_full_unstemmed |
Field-Induced Single-Ion Magnet Behaviour in Two New Cobalt(II) Coordination Polymers with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine |
title_sort |
field-induced single-ion magnet behaviour in two new cobalt(ii) coordination polymers with 2,4,6-tris(4-pyridyl)-1,3,5-triazine |
publisher |
MDPI AG |
series |
Inorganics |
issn |
2304-6740 |
publishDate |
2017-12-01 |
description |
We herein reported the syntheses, crystal structures, and magnetic properties of a two-dimensional coordination polymer {[CoII(TPT)2/3(H2O)4][CH3COO]2·(H2O)4}n (1) and a chain compound {[CoII(TPT)2(CHOO)2(H2O)2]}n (2) based on the 2,4,6-Tris(4-pyridyl)-1,3,5-triazine (TPT) ligand. Structure analyses showed that complex 1 had a cationic hexagonal framework structure, while 2 was a neutral zig-zag chain structure with different distorted octahedral coordination environments. Magnetic measurements revealed that both complexes exhibit large easy-plane magnetic anisotropy with the zero-field splitting parameter D = 47.7 and 62.1 cm−1 for 1 and 2, respectively. This magnetic anisotropy leads to the field-induced slow magnetic relaxation behaviour. However, their magnetic dynamics are quite different; while complex 1 experienced a dominating thermally activated Orbach relaxation at the whole measured temperature region, 2 exhibited multiple relaxation pathways involving direct, Raman, and quantum tunneling (QTM) processes at low temperatures and Orbach relaxation at high temperatures. The present complexes enlarge the family of framework-based single-ion magnets (SIMs) and highlight the significance of the structural dimensionality to the final magnetic properties. |
topic |
single-ion magnet cobalt(II) magnetic anisotropy coordination polymers |
url |
https://www.mdpi.com/2304-6740/5/4/90 |
work_keys_str_mv |
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