Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin

A one-pot synthesis of bulky bis-pocket A3B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxida...

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Main Authors:	Ze-Yu Liu, Mian HR Mahmood, Jian-Zhong Wu, Shu-Bao Yang, Hai-Yang Liu
Format:	Article
Language:	English
Published:	MDPI AG 2017-11-01
Series:	Molecules
Subjects:	meso-cyano porphyrin One-pot synthesis pyrrole-aldehyde condensation trifluoroacetic acid
Online Access:	https://www.mdpi.com/1420-3049/22/11/1941

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spelling	doaj-7380ff5da03a406888bfb48087fc23d32020-11-24T23:54:56ZengMDPI AGMolecules1420-30492017-11-012211194110.3390/molecules22111941molecules22111941Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano PorphyrinZe-Yu Liu0Mian HR Mahmood1Jian-Zhong Wu2Shu-Bao Yang3Hai-Yang Liu4School of Chemistry and Environment, South China Normal University, Guangzhou 510006, ChinaDepartment of Chemistry, South China University of Technology, Guangzhou 510641, ChinaSchool of Chemistry and Environment, South China Normal University, Guangzhou 510006, ChinaDepartment of Chemistry, South China University of Technology, Guangzhou 510641, ChinaDepartment of Chemistry, South China University of Technology, Guangzhou 510641, ChinaA one-pot synthesis of bulky bis-pocket A3B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.https://www.mdpi.com/1420-3049/22/11/1941meso-cyano porphyrinOne-pot synthesispyrrole-aldehyde condensationtrifluoroacetic acid
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Ze-Yu Liu Mian HR Mahmood Jian-Zhong Wu Shu-Bao Yang Hai-Yang Liu
spellingShingle	Ze-Yu Liu Mian HR Mahmood Jian-Zhong Wu Shu-Bao Yang Hai-Yang Liu Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin Molecules meso-cyano porphyrin One-pot synthesis pyrrole-aldehyde condensation trifluoroacetic acid
author_facet	Ze-Yu Liu Mian HR Mahmood Jian-Zhong Wu Shu-Bao Yang Hai-Yang Liu
author_sort	Ze-Yu Liu
title	Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
title_short	Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
title_full	Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
title_fullStr	Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
title_full_unstemmed	Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
title_sort	unexpected synthesis of a bulky bis-pocket a3b-type meso-cyano porphyrin
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2017-11-01
description	A one-pot synthesis of bulky bis-pocket A3B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.
topic	meso-cyano porphyrin One-pot synthesis pyrrole-aldehyde condensation trifluoroacetic acid
url	https://www.mdpi.com/1420-3049/22/11/1941
work_keys_str_mv	AT zeyuliu unexpectedsynthesisofabulkybispocketa3btypemesocyanoporphyrin AT mianhrmahmood unexpectedsynthesisofabulkybispocketa3btypemesocyanoporphyrin AT jianzhongwu unexpectedsynthesisofabulkybispocketa3btypemesocyanoporphyrin AT shubaoyang unexpectedsynthesisofabulkybispocketa3btypemesocyanoporphyrin AT haiyangliu unexpectedsynthesisofabulkybispocketa3btypemesocyanoporphyrin
_version_	1725464299323785216

Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin

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