Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines

Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines

An efficient chemoselective reduction of aromatic nitro compounds to corresponding amino analogues was achieved using palladium/sucrose (Pd/S) nanoparticles as an eco friendly catalyst, a green approach formate in ethanol at RT. The reductions are fruitfully carried out in presence of various other...

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Main Authors: Dasi Samsonu, Manuri Brahmayya, Boddeti Govindh, Y.L.N. Murthy
Format: Article
Language:English
Published: Elsevier 2018-06-01
Series:South African Journal of Chemical Engineering
Online Access:http://www.sciencedirect.com/science/article/pii/S1026918516300804
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spelling doaj-73b74ca755054a6c8a4f95e67bcaa2d92020-11-24T22:56:53ZengElsevierSouth African Journal of Chemical Engineering1026-91852018-06-0125110115Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful aminesDasi Samsonu0Manuri Brahmayya1Boddeti Govindh2Y.L.N. Murthy3Department of Organic Chemistry and FDW, Andhra University, China Waltair Road, Visakhapatnam, 530003, India; Corresponding author.Department of Environmental Engineering Safety and Health, Hung Kuang University, Shalu, Taichung, TaiwanDepartment of H & S, Raghu Institute of Technology, Visakhapatnam, Andhra Pradesh, IndiaDepartment of Organic Chemistry and FDW, Andhra University, China Waltair Road, Visakhapatnam, 530003, IndiaAn efficient chemoselective reduction of aromatic nitro compounds to corresponding amino analogues was achieved using palladium/sucrose (Pd/S) nanoparticles as an eco friendly catalyst, a green approach formate in ethanol at RT. The reductions are fruitfully carried out in presence of various other reducible functional groups such as halo, alkoxy, carbonyl, and cyanide etc. The reactions are worthy and high yielding (100%). Keywords: Pd/sucrose nanoparticles, Eco friendly, Reduction, Amine formation, Methodolgy, Characterizationshttp://www.sciencedirect.com/science/article/pii/S1026918516300804
collection DOAJ
language English
format Article
sources DOAJ
author Dasi Samsonu
Manuri Brahmayya
Boddeti Govindh
Y.L.N. Murthy
spellingShingle Dasi Samsonu
Manuri Brahmayya
Boddeti Govindh
Y.L.N. Murthy
Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
South African Journal of Chemical Engineering
author_facet Dasi Samsonu
Manuri Brahmayya
Boddeti Govindh
Y.L.N. Murthy
author_sort Dasi Samsonu
title Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
title_short Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
title_full Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
title_fullStr Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
title_full_unstemmed Green synthesis & catalytic study of sucrose stabilized Pd nanoparticles in reduction of nitro compounds to useful amines
title_sort green synthesis & catalytic study of sucrose stabilized pd nanoparticles in reduction of nitro compounds to useful amines
publisher Elsevier
series South African Journal of Chemical Engineering
issn 1026-9185
publishDate 2018-06-01
description An efficient chemoselective reduction of aromatic nitro compounds to corresponding amino analogues was achieved using palladium/sucrose (Pd/S) nanoparticles as an eco friendly catalyst, a green approach formate in ethanol at RT. The reductions are fruitfully carried out in presence of various other reducible functional groups such as halo, alkoxy, carbonyl, and cyanide etc. The reactions are worthy and high yielding (100%). Keywords: Pd/sucrose nanoparticles, Eco friendly, Reduction, Amine formation, Methodolgy, Characterizations
url http://www.sciencedirect.com/science/article/pii/S1026918516300804
work_keys_str_mv AT dasisamsonu greensynthesiscatalyticstudyofsucrosestabilizedpdnanoparticlesinreductionofnitrocompoundstousefulamines
AT manuribrahmayya greensynthesiscatalyticstudyofsucrosestabilizedpdnanoparticlesinreductionofnitrocompoundstousefulamines
AT boddetigovindh greensynthesiscatalyticstudyofsucrosestabilizedpdnanoparticlesinreductionofnitrocompoundstousefulamines
AT ylnmurthy greensynthesiscatalyticstudyofsucrosestabilizedpdnanoparticlesinreductionofnitrocompoundstousefulamines
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