Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)

Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)

The crystal structure of the title compound, [Cr(C8H8NO)3], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr3+ cation and three N-methylsalicylaldiminate anions. The metal cation is octahedrally coordinated by three N,O-chelating N-methylsalicylaldiminate ligands,...

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Main Authors: Jessica Hilbert, Sven Kabus, Christian Näther, Wolfgang Bensch
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
chromium(III)
N-methylsalicylaldiminate
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015023038
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spelling doaj-7404b8b0e7a8458595d40b25f04df4ed2020-11-24T21:45:46ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112m247m24810.1107/S2056989015023038wm5245Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)Jessica Hilbert0Sven Kabus1Christian Näther2Wolfgang Bensch3Institute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Strasse 2, 24118 Kiel, GermanyThe crystal structure of the title compound, [Cr(C8H8NO)3], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr3+ cation and three N-methylsalicylaldiminate anions. The metal cation is octahedrally coordinated by three N,O-chelating N-methylsalicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked via C—H...O hydrogen-bonding interactions into chains propagating parallel to the c axis.http://scripts.iucr.org/cgi-bin/paper?S2056989015023038crystal structurechromium(III)N-methylsalicylaldiminatehydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Jessica Hilbert
Sven Kabus
Christian Näther
Wolfgang Bensch
spellingShingle Jessica Hilbert
Sven Kabus
Christian Näther
Wolfgang Bensch
Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
chromium(III)
N-methylsalicylaldiminate
hydrogen bonding
author_facet Jessica Hilbert
Sven Kabus
Christian Näther
Wolfgang Bensch
author_sort Jessica Hilbert
title Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
title_short Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
title_full Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
title_fullStr Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
title_full_unstemmed Crystal structure of tris(N-methylsalicylaldiminato-κ2N,O)chromium(III)
title_sort crystal structure of tris(n-methylsalicylaldiminato-κ2n,o)chromium(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-12-01
description The crystal structure of the title compound, [Cr(C8H8NO)3], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr3+ cation and three N-methylsalicylaldiminate anions. The metal cation is octahedrally coordinated by three N,O-chelating N-methylsalicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked via C—H...O hydrogen-bonding interactions into chains propagating parallel to the c axis.
topic crystal structure
chromium(III)
N-methylsalicylaldiminate
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S2056989015023038
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AT svenkabus crystalstructureoftrisnmethylsalicylaldiminatok2nochromiumiii
AT christiannather crystalstructureoftrisnmethylsalicylaldiminatok2nochromiumiii
AT wolfgangbensch crystalstructureoftrisnmethylsalicylaldiminatok2nochromiumiii
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