The next generation of low-cost personal air quality sensors for quantitative exposure monitoring

• Main Authors: R. Piedrahita, Y. Xiang, N. Masson, J. Ortega, A. Collier, Y. Jiang, K. Li, R. P. Dick, Q. Lv, M. Hannigan, L. Shang
• Format: Article
• Language: English
• Published: Copernicus Publications 2014-10-01
• Series: Atmospheric Measurement Techniques
• Online Access: http://www.atmos-meas-tech.net/7/3325/2014/amt-7-3325-2014.pdf
• ISSN: 1867-1381; 1867-8548

Advances in embedded systems and low-cost gas sensors are enabling a new wave of low-cost air quality monitoring tools. Our team has been engaged in the development of low-cost, wearable, air quality monitors (M-Pods) using the Arduino platform. These M-Pods house two types of sensors – commercially available metal oxide semiconductor (MOx) sensors used to measure CO, O₃, NO₂, and total VOCs, and NDIR sensors used to measure CO₂. The MOx sensors are low in cost and show high sensitivity near ambient levels; however they display non-linear output signals and have cross-sensitivity effects. Thus, a quantification system was developed to convert the MOx sensor signals into concentrations. <br><br> We conducted two types of validation studies – first, deployments at a regulatory monitoring station in Denver, Colorado, and second, a user study. In the two deployments (at the regulatory monitoring station), M-Pod concentrations were determined using collocation calibrations and laboratory calibration techniques. M-Pods were placed near regulatory monitors to derive calibration function coefficients using the regulatory monitors as the standard. The form of the calibration function was derived based on laboratory experiments. We discuss various techniques used to estimate measurement uncertainties. <br><br> The deployments revealed that collocation calibrations provide more accurate concentration estimates than laboratory calibrations. During collocation calibrations, median standard errors ranged between 4.0–6.1 ppb for O₃, 6.4–8.4 ppb for NO₂, 0.28–0.44 ppm for CO, and 16.8 ppm for CO₂. Median signal to noise (S / N) ratios for the M-Pod sensors were higher than the regulatory instruments: for NO₂, 3.6 compared to 23.4; for O₃, 1.4 compared to 1.6; for CO, 1.1 compared to 10.0; and for CO₂, 42.2 compared to 300–500. By contrast, lab calibrations added bias and made it difficult to cover the necessary range of environmental conditions to obtain a good calibration. <br><br> A separate user study was also conducted to assess uncertainty estimates and sensor variability. In this study, 9 M-Pods were calibrated via collocation multiple times over 4 weeks, and sensor drift was analyzed, with the result being a calibration function that included baseline drift. Three pairs of M-Pods were deployed, while users individually carried the other three. <br><br> The user study suggested that inter-M-Pod variability between paired units was on the same order as calibration uncertainty; however, it is difficult to make conclusions about the actual personal exposure levels due to the level of user engagement. The user study provided real-world sensor drift data, showing limited CO drift (under −0.05 ppm day⁻¹), and higher for O₃ (−2.6 to 2.0 ppb day⁻¹), NO₂ (−1.56 to 0.51 ppb day⁻¹), and CO₂ (−4.2 to 3.1 ppm day⁻¹). Overall, the user study confirmed the utility of the M-Pod as a low-cost tool to assess personal exposure.