THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS

THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS

The heteronuclear complexes on the base of meso-tetra-crown-ether substituted porphyrins of «sandwich»-type which two ytterbium ions coordinated with porphyrin macrocycles, and four cations of alkaline metals (Na, K, Cs) situated between the cavities of benzo-12-crown-4-, benzo-15-crown-5- and benzo...

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Main Author: N. V. Rusakova
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2016-04-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
Subjects:
комплекси, ітербій, лужні метали, аніони, люмінесценція
Online Access:http://heraldchem.onu.edu.ua/article/view/67165
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spelling doaj-754ae4c964be4121b3e2e4e55cd23e7b2020-11-24T22:45:48ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632016-04-01144748010.18524/2304-0947.2009.4.6716567165THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINSN. V. Rusakova0Фізико-хімічний інститут ім. О. В. Богатського НАН України, Відділ хімії лантанідівThe heteronuclear complexes on the base of meso-tetra-crown-ether substituted porphyrins of «sandwich»-type which two ytterbium ions coordinated with porphyrin macrocycles, and four cations of alkaline metals (Na, K, Cs) situated between the cavities of benzo-12-crown-4-, benzo-15-crown-5- and benzo-18-crown-6-ethers, respectively, were obtained. The influence of anion nature of salts (bromide, nitrate, thiocyanate) on 4f-luminescence of Yb8+ ions in these complexes were analyzed.http://heraldchem.onu.edu.ua/article/view/67165комплекси, ітербій, лужні метали, аніони, люмінесценція
collection DOAJ
language English
format Article
sources DOAJ
author N. V. Rusakova
spellingShingle N. V. Rusakova
THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
комплекси, ітербій, лужні метали, аніони, люмінесценція
author_facet N. V. Rusakova
author_sort N. V. Rusakova
title THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
title_short THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
title_full THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
title_fullStr THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
title_full_unstemmed THE INFLUENCE OF ANION NATURE OF ALKALINE METAL SALT ON SPECTRAL-LUMINESCENT PROPERTIES OF F-S-HETERONUCLEAR COMPLEXES ON THE BASE OF CROWN-PORPHYRINS
title_sort influence of anion nature of alkaline metal salt on spectral-luminescent properties of f-s-heteronuclear complexes on the base of crown-porphyrins
publisher Odessa I. I. Mechnikov National University
series Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
issn 2304-0947
2414-5963
publishDate 2016-04-01
description The heteronuclear complexes on the base of meso-tetra-crown-ether substituted porphyrins of «sandwich»-type which two ytterbium ions coordinated with porphyrin macrocycles, and four cations of alkaline metals (Na, K, Cs) situated between the cavities of benzo-12-crown-4-, benzo-15-crown-5- and benzo-18-crown-6-ethers, respectively, were obtained. The influence of anion nature of salts (bromide, nitrate, thiocyanate) on 4f-luminescence of Yb8+ ions in these complexes were analyzed.
topic комплекси, ітербій, лужні метали, аніони, люмінесценція
url http://heraldchem.onu.edu.ua/article/view/67165
work_keys_str_mv AT nvrusakova theinfluenceofanionnatureofalkalinemetalsaltonspectralluminescentpropertiesoffsheteronuclearcomplexesonthebaseofcrownporphyrins
AT nvrusakova influenceofanionnatureofalkalinemetalsaltonspectralluminescentpropertiesoffsheteronuclearcomplexesonthebaseofcrownporphyrins
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