Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals
3 at.% Tm, x at.% Y:CaF2 crystals (x=0, 0.5, 1, 2, and 3) were grown by the vertical Bridgman method and investigated. Codoping Y3+ ions can manipulate the local structure of Tm3+ ions in the CaF2 crystal and then improve the spectroscopic properties. Compared with 3 at.% Tm:CaF2, 3 at.% Tm, 3 at.%...
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doaj-759aa0fa8ab84c4a935ef77767455a1f2020-11-25T00:55:05ZengHindawi LimitedInternational Journal of Optics1687-93841687-93922018-01-01201810.1155/2018/85923598592359Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single CrystalsJingxin Ding0Beibei Zhao1Weiwei Ma2Hao Yu3Xiaobo Qian4Lingchen Kong5Jingya Wang6Guoqiang Xie7Anhua Wu8Fanming Zeng9Liangbi Su10Synthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaKey Laboratory for Laser Plasmas (Ministry of Education), Collaborative Innovation Center of IFSA (CICIFSA), Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaKey Laboratory for Laser Plasmas (Ministry of Education), Collaborative Innovation Center of IFSA (CICIFSA), Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaSchool of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, ChinaSynthetic Single Crystal Research Center, Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China3 at.% Tm, x at.% Y:CaF2 crystals (x=0, 0.5, 1, 2, and 3) were grown by the vertical Bridgman method and investigated. Codoping Y3+ ions can manipulate the local structure of Tm3+ ions in the CaF2 crystal and then improve the spectroscopic properties. Compared with 3 at.% Tm:CaF2, 3 at.% Tm, 3 at.% Y:CaF2 crystal has several advantages. Firstly, the absorption cross section is improved from 0.35 × 10−20 cm−2 to 0.45 × 10−20 cm−2 at 767 nm, and the fluorescence intensity had elevated 3.4 times. Secondly, the linewidth of the fluorescence spectrum and lifetime also increased from 164 nm to 191 nm and from 6.16 ms to 8.15 ms at room temperature, respectively. Furthermore, quantum efficiency improved from 58.2% to 80.3%. The maximum laser output power of 583 mW and slope efficiency of 25.3% were achieved in 3 at.% Tm, 3 at.% Y:CaF2 crystal under 790 nm diode pumping.http://dx.doi.org/10.1155/2018/8592359 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jingxin Ding Beibei Zhao Weiwei Ma Hao Yu Xiaobo Qian Lingchen Kong Jingya Wang Guoqiang Xie Anhua Wu Fanming Zeng Liangbi Su |
spellingShingle |
Jingxin Ding Beibei Zhao Weiwei Ma Hao Yu Xiaobo Qian Lingchen Kong Jingya Wang Guoqiang Xie Anhua Wu Fanming Zeng Liangbi Su Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals International Journal of Optics |
author_facet |
Jingxin Ding Beibei Zhao Weiwei Ma Hao Yu Xiaobo Qian Lingchen Kong Jingya Wang Guoqiang Xie Anhua Wu Fanming Zeng Liangbi Su |
author_sort |
Jingxin Ding |
title |
Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals |
title_short |
Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals |
title_full |
Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals |
title_fullStr |
Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals |
title_full_unstemmed |
Optical Spectra Properties and Continuous-Wave Laser Performance of Tm,Y:CaF2 Single Crystals |
title_sort |
optical spectra properties and continuous-wave laser performance of tm,y:caf2 single crystals |
publisher |
Hindawi Limited |
series |
International Journal of Optics |
issn |
1687-9384 1687-9392 |
publishDate |
2018-01-01 |
description |
3 at.% Tm, x at.% Y:CaF2 crystals (x=0, 0.5, 1, 2, and 3) were grown by the vertical Bridgman method and investigated. Codoping Y3+ ions can manipulate the local structure of Tm3+ ions in the CaF2 crystal and then improve the spectroscopic properties. Compared with 3 at.% Tm:CaF2, 3 at.% Tm, 3 at.% Y:CaF2 crystal has several advantages. Firstly, the absorption cross section is improved from 0.35 × 10−20 cm−2 to 0.45 × 10−20 cm−2 at 767 nm, and the fluorescence intensity had elevated 3.4 times. Secondly, the linewidth of the fluorescence spectrum and lifetime also increased from 164 nm to 191 nm and from 6.16 ms to 8.15 ms at room temperature, respectively. Furthermore, quantum efficiency improved from 58.2% to 80.3%. The maximum laser output power of 583 mW and slope efficiency of 25.3% were achieved in 3 at.% Tm, 3 at.% Y:CaF2 crystal under 790 nm diode pumping. |
url |
http://dx.doi.org/10.1155/2018/8592359 |
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