Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
The structure of the title compound, [Mg(C10H6O6S2)(C3H7NO)2]n, consists of MgO6 octahedra (overline{1} symmetry) connected to naphthalene-1,5-disulfonate ligands (overline{1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere o...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-06-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810017952 |
Summary: | The structure of the title compound, [Mg(C10H6O6S2)(C3H7NO)2]n, consists of MgO6 octahedra (overline{1} symmetry) connected to naphthalene-1,5-disulfonate ligands (overline{1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg2+ atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio. |
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ISSN: | 1600-5368 |