Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]

Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]

The structure of the title compound, [Mg(C10H6O6S2)(C3H7NO)2]n, consists of MgO6 octahedra (overline{1} symmetry) connected to naphthalene-1,5-disulfonate ligands (overline{1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere o...

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Main Authors: Lauren A. Borkowski, Debasis Banerjee, John B. Parise
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810017952
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spelling doaj-75ee00b9cd154310a02591886c1c671a2020-11-25T02:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m691m69210.1107/S1600536810017952Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]Lauren A. BorkowskiDebasis BanerjeeJohn B. PariseThe structure of the title compound, [Mg(C10H6O6S2)(C3H7NO)2]n, consists of MgO6 octahedra (overline{1} symmetry) connected to naphthalene-1,5-disulfonate ligands (overline{1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg2+ atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio. http://scripts.iucr.org/cgi-bin/paper?S1600536810017952
collection DOAJ
language English
format Article
sources DOAJ
author Lauren A. Borkowski
Debasis Banerjee
John B. Parise
spellingShingle Lauren A. Borkowski
Debasis Banerjee
John B. Parise
Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
Acta Crystallographica Section E
author_facet Lauren A. Borkowski
Debasis Banerjee
John B. Parise
author_sort Lauren A. Borkowski
title Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
title_short Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
title_full Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
title_fullStr Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
title_full_unstemmed Poly[bis(N,N-dimethylformamide-κO)(μ4-naphthalene-1,5-disulfonato)magnesium(II)]
title_sort poly[bis(n,n-dimethylformamide-κo)(μ4-naphthalene-1,5-disulfonato)magnesium(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description The structure of the title compound, [Mg(C10H6O6S2)(C3H7NO)2]n, consists of MgO6 octahedra (overline{1} symmetry) connected to naphthalene-1,5-disulfonate ligands (overline{1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg2+ atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810017952
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AT debasisbanerjee polybisnndimethylformamideamp954oamp9564naphthalene15disulfonatomagnesiumii
AT johnbparise polybisnndimethylformamideamp954oamp9564naphthalene15disulfonatomagnesiumii
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