Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium
In the structure of the title compound, [Cd(C8H6NO4)2(C3H10N2)2], the CdII atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The CdII atom has an overall octahedral coordination environment. Several ty...
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International Union of Crystallography
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doaj-763d09ce6a2d4cd4962e298a57161b342020-11-24T23:28:24ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-02-0172222622810.1107/S2056989016000943wm5258Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmiumIan M. Rahn0Carlos L. Crawford1Zerihun Assefa2Jeffery Hendrich3Richard E. Sykora4University of North Carolina–Chapel Hill, USA1601 E Market St., Department of Chemistry, North Carolina A&T State University, Greensboro, NC 27411, USA1601 E Market St., Department of Chemistry, North Carolina A&T State University, Greensboro, NC 27411, USAUniversity of South Alabama, Department of Chemistry, Mobile, AL 36688-0002, USAUniversity of South Alabama, Department of Chemistry, Mobile, AL 36688-0002, USAIn the structure of the title compound, [Cd(C8H6NO4)2(C3H10N2)2], the CdII atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The CdII atom has an overall octahedral coordination environment. Several types of hydrogen-bonding interactions are evident. Both intra- and intermolecular interactions occur between the amino groups and the O atoms of the acetate group. These N—H...O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak intermolecular C—H...O interactions involving the nitro groups exist, leading to the formation of a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S2056989016000943crystal structurecadmium complex1,3-diaminopropanenitrophenylacetic acid |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ian M. Rahn Carlos L. Crawford Zerihun Assefa Jeffery Hendrich Richard E. Sykora |
spellingShingle |
Ian M. Rahn Carlos L. Crawford Zerihun Assefa Jeffery Hendrich Richard E. Sykora Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium Acta Crystallographica Section E: Crystallographic Communications crystal structure cadmium complex 1,3-diaminopropane nitrophenylacetic acid |
author_facet |
Ian M. Rahn Carlos L. Crawford Zerihun Assefa Jeffery Hendrich Richard E. Sykora |
author_sort |
Ian M. Rahn |
title |
Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium |
title_short |
Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium |
title_full |
Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium |
title_fullStr |
Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium |
title_full_unstemmed |
Crystal structure of bis(1,3-diaminopropane-κ2N,N′)bis[2-(4-nitrophenyl)acetato-κO]cadmium |
title_sort |
crystal structure of bis(1,3-diaminopropane-κ2n,n′)bis[2-(4-nitrophenyl)acetato-κo]cadmium |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2016-02-01 |
description |
In the structure of the title compound, [Cd(C8H6NO4)2(C3H10N2)2], the CdII atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The CdII atom has an overall octahedral coordination environment. Several types of hydrogen-bonding interactions are evident. Both intra- and intermolecular interactions occur between the amino groups and the O atoms of the acetate group. These N—H...O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak intermolecular C—H...O interactions involving the nitro groups exist, leading to the formation of a three-dimensional network structure. |
topic |
crystal structure cadmium complex 1,3-diaminopropane nitrophenylacetic acid |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989016000943 |
work_keys_str_mv |
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