Utilization of steric hindrance of alkyl lithium-based initiator to synthesize high 1,4 unit-containing hydroxyl- terminated polybutadiene
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structu...
Main Authors: | Xin Min, Xiaodong Fan, Jie Liu |
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Format: | Article |
Language: | English |
Published: |
The Royal Society
2018-01-01
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Series: | Royal Society Open Science |
Subjects: | |
Online Access: | https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.180156 |
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