tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate
The molecule of the title compound, C16H23N3O6, is twisted about the chiral C atom with the dihedral angle formed between the amide residues being 76.9 (3)°. Overall, the molecule is curved with the terminal organic groups lying to the same side. The conformation about the...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025293 |
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doaj-7880d8282c344514a1f58e6c277b109e2020-11-25T02:40:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678o1888o188910.1107/S1600536811025293tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamateJames L. WardellMarcus V. N. de SouzaAlessandra C. PinheiroEdward R. T. TiekinkSolange M. S. V. WardellThe molecule of the title compound, C16H23N3O6, is twisted about the chiral C atom with the dihedral angle formed between the amide residues being 76.9 (3)°. Overall, the molecule is curved with the terminal organic groups lying to the same side. The conformation about the imine bond [1.291 (5) Å] is E and an intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, O—H...O and N—H...O hydrogen bonds involving the hydroxy, amine and carbonyl groups lead to the formation of supramolecular layers, which stack along the c-axis direction.http://scripts.iucr.org/cgi-bin/paper?S1600536811025293 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
James L. Wardell Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell |
| spellingShingle |
James L. Wardell Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate Acta Crystallographica Section E |
| author_facet |
James L. Wardell Marcus V. N. de Souza Alessandra C. Pinheiro Edward R. T. Tiekink Solange M. S. V. Wardell |
| author_sort |
James L. Wardell |
| title |
tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| title_short |
tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| title_full |
tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| title_fullStr |
tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| title_full_unstemmed |
tert-Butyl N-((1S)-2-hydroxy-1-{N′-[(E)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| title_sort |
tert-butyl n-((1s)-2-hydroxy-1-{n′-[(e)-2-hydroxy-4-methoxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-08-01 |
| description |
The molecule of the title compound, C16H23N3O6, is twisted about the chiral C atom with the dihedral angle formed between the amide residues being 76.9 (3)°. Overall, the molecule is curved with the terminal organic groups lying to the same side. The conformation about the imine bond [1.291 (5) Å] is E and an intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, O—H...O and N—H...O hydrogen bonds involving the hydroxy, amine and carbonyl groups lead to the formation of supramolecular layers, which stack along the c-axis direction. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811025293 |
| work_keys_str_mv |
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