(Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate

(Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate

In the structure of the title complex, [Ni(CH3CO2)(C14H23N5O)(H2O)]ClO4·H2O, the NiII centre has a distorted octahedral environment defined by one O and three N atoms derived from the tetradentate ligand, and two O atoms, one from a water molecule and the other from an acetate anion. Th...

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Main Authors: Jia Zhou, Mouhai Shu
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812007970
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spelling doaj-788c6329895a422f801893696ccd88102020-11-25T03:27:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m399m39910.1107/S1600536812007970(Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrateJia ZhouMouhai ShuIn the structure of the title complex, [Ni(CH3CO2)(C14H23N5O)(H2O)]ClO4·H2O, the NiII centre has a distorted octahedral environment defined by one O and three N atoms derived from the tetradentate ligand, and two O atoms, one from a water molecule and the other from an acetate anion. The molecules are connected into a three-dimensional architecture by O—H...O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).http://scripts.iucr.org/cgi-bin/paper?S1600536812007970
collection DOAJ
language English
format Article
sources DOAJ
author Jia Zhou
Mouhai Shu
spellingShingle Jia Zhou
Mouhai Shu
(Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
Acta Crystallographica Section E
author_facet Jia Zhou
Mouhai Shu
author_sort Jia Zhou
title (Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_short (Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_full (Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_fullStr (Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_full_unstemmed (Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_sort (acetato-κo)(aqua-κo)(2-{bis[(3,5-dimethyl-1h-pyrazol-1-yl-κn2)methyl]amino-κn}ethanol-κo)nickel(ii) perchlorate monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description In the structure of the title complex, [Ni(CH3CO2)(C14H23N5O)(H2O)]ClO4·H2O, the NiII centre has a distorted octahedral environment defined by one O and three N atoms derived from the tetradentate ligand, and two O atoms, one from a water molecule and the other from an acetate anion. The molecules are connected into a three-dimensional architecture by O—H...O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).
url http://scripts.iucr.org/cgi-bin/paper?S1600536812007970
work_keys_str_mv AT jiazhou acetatoamp954oaquaamp954o2bis35dimethyl1hpyrazol1ylamp954n2methylaminoamp954nethanolamp954onickeliiperchloratemonohydrate
AT mouhaishu acetatoamp954oaquaamp954o2bis35dimethyl1hpyrazol1ylamp954n2methylaminoamp954nethanolamp954onickeliiperchloratemonohydrate
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