Crystal structure of 4-chloro-2-iodoaniline

Crystal structure of 4-chloro-2-iodoaniline

In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N—H...N hydrogen bonding, creating [100] chains. A Cl...I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring molecules reveal highly offset π-stacking characterized by a centroid–centroid distan...

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Bibliographic Details
Main Authors: Taylor R. Quinn, Joseph M. Tanski
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
halogen–halogen interaction
aniline
π-stacking
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814016869
Description
Summary:In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N—H...N hydrogen bonding, creating [100] chains. A Cl...I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring molecules reveal highly offset π-stacking characterized by a centroid–centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
ISSN:1600-5368

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