Crystal structure of 4-chloro-2-iodoaniline

Crystal structure of 4-chloro-2-iodoaniline

In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N—H...N hydrogen bonding, creating [100] chains. A Cl...I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring molecules reveal highly offset π-stacking characterized by a centroid–centroid distan...

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Main Authors: Taylor R. Quinn, Joseph M. Tanski
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
halogen–halogen interaction
aniline
π-stacking
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814016869
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spelling doaj-78b82e963cfe46d78a56c2e5ed8610042020-11-25T00:12:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o944o94510.1107/S1600536814016869jj2191Crystal structure of 4-chloro-2-iodoanilineTaylor R. Quinn0Joseph M. Tanski1Department of Chemistry, Vassar College, Poughkeepsie, NY 12604, USADepartment of Chemistry, Vassar College, Poughkeepsie, NY 12604, USAIn the crystal structure of the title compound, C6H5ClIN, the amino group engages in N—H...N hydrogen bonding, creating [100] chains. A Cl...I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring molecules reveal highly offset π-stacking characterized by a centroid–centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536814016869crystal structurehalogen–halogen interactionanilineπ-stacking
collection DOAJ
language English
format Article
sources DOAJ
author Taylor R. Quinn
Joseph M. Tanski
spellingShingle Taylor R. Quinn
Joseph M. Tanski
Crystal structure of 4-chloro-2-iodoaniline
Acta Crystallographica Section E
crystal structure
halogen–halogen interaction
aniline
π-stacking
author_facet Taylor R. Quinn
Joseph M. Tanski
author_sort Taylor R. Quinn
title Crystal structure of 4-chloro-2-iodoaniline
title_short Crystal structure of 4-chloro-2-iodoaniline
title_full Crystal structure of 4-chloro-2-iodoaniline
title_fullStr Crystal structure of 4-chloro-2-iodoaniline
title_full_unstemmed Crystal structure of 4-chloro-2-iodoaniline
title_sort crystal structure of 4-chloro-2-iodoaniline
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-09-01
description In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N—H...N hydrogen bonding, creating [100] chains. A Cl...I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring molecules reveal highly offset π-stacking characterized by a centroid–centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
topic crystal structure
halogen–halogen interaction
aniline
π-stacking
url http://scripts.iucr.org/cgi-bin/paper?S1600536814016869
work_keys_str_mv AT taylorrquinn crystalstructureof4chloro2iodoaniline
AT josephmtanski crystalstructureof4chloro2iodoaniline
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