Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]

In the title compound, {[Mn(C14H16N5O3)2]·2H2O}n, the MnII atom (site symmetry overline{1}) exhibits a distorted trans-MnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6...

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Bibliographic Details
Main Authors: Zhe An, Wei-Ping Hu, Jing Huang
Format: Article
Language:English
Published: International Union of Crystallography 2008-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808006533
Description
Summary:In the title compound, {[Mn(C14H16N5O3)2]·2H2O}n, the MnII atom (site symmetry overline{1}) exhibits a distorted trans-MnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylate anions. An N—H...O hydrogen bond is present in the crystal structure. The extended two-dimensional structure is a square grid and the disordered uncoordinated water molecules occupy cavities within the grid.
ISSN:1600-5368