β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives

Porphyrins bearing formyl or vinyl groups have been explored as starting materials to prepare new compounds with adequate features for different applications. In this review it is discussed mainly synthetic strategies based on the reaction of meso-tetraarylporphyrins bearing those groups at β-pyrrol...

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Main Authors:	Ana F. R. Cerqueira, Nuno M. M. Moura, Vanda Vaz Serra, M. Amparo F. Faustino, Augusto C. Tomé, José A. S. Cavaleiro, M. Graça P. M. S. Neves
Format:	Article
Language:	English
Published:	MDPI AG 2017-07-01
Series:	Molecules
Subjects:	porphyrins formyl group vinyl group methylene active compounds imines pericylic reactions
Online Access:	https://www.mdpi.com/1420-3049/22/8/1269

id	doaj-79af4e79590f42e786f794be5b2960f0
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spelling	doaj-79af4e79590f42e786f794be5b2960f02020-11-25T01:17:47ZengMDPI AGMolecules1420-30492017-07-01228126910.3390/molecules22081269molecules22081269β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin DerivativesAna F. R. Cerqueira0Nuno M. M. Moura1Vanda Vaz Serra2M. Amparo F. Faustino3Augusto C. Tomé4José A. S. Cavaleiro5M. Graça P. M. S. Neves6Department of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, PortugalPorphyrins bearing formyl or vinyl groups have been explored as starting materials to prepare new compounds with adequate features for different applications. In this review it is discussed mainly synthetic strategies based on the reaction of meso-tetraarylporphyrins bearing those groups at β-pyrrolic positions. The use of some of the obtained porphyrin derivatives for further transformations, namely via pericyclic reactions, is also highlighted.https://www.mdpi.com/1420-3049/22/8/1269porphyrinsformyl groupvinyl groupmethylene active compoundsiminespericylic reactions
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Ana F. R. Cerqueira Nuno M. M. Moura Vanda Vaz Serra M. Amparo F. Faustino Augusto C. Tomé José A. S. Cavaleiro M. Graça P. M. S. Neves
spellingShingle	Ana F. R. Cerqueira Nuno M. M. Moura Vanda Vaz Serra M. Amparo F. Faustino Augusto C. Tomé José A. S. Cavaleiro M. Graça P. M. S. Neves β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives Molecules porphyrins formyl group vinyl group methylene active compounds imines pericylic reactions
author_facet	Ana F. R. Cerqueira Nuno M. M. Moura Vanda Vaz Serra M. Amparo F. Faustino Augusto C. Tomé José A. S. Cavaleiro M. Graça P. M. S. Neves
author_sort	Ana F. R. Cerqueira
title	β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
title_short	β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
title_full	β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
title_fullStr	β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
title_full_unstemmed	β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
title_sort	β-formyl- and β-vinylporphyrins: magic building blocks for novel porphyrin derivatives
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2017-07-01
description	Porphyrins bearing formyl or vinyl groups have been explored as starting materials to prepare new compounds with adequate features for different applications. In this review it is discussed mainly synthetic strategies based on the reaction of meso-tetraarylporphyrins bearing those groups at β-pyrrolic positions. The use of some of the obtained porphyrin derivatives for further transformations, namely via pericyclic reactions, is also highlighted.
topic	porphyrins formyl group vinyl group methylene active compounds imines pericylic reactions
url	https://www.mdpi.com/1420-3049/22/8/1269
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β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives

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