Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate

Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate

In the title complex, [Co(CN)2(C18H18N4)]PF6, the CoIII atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The CoIII atom exhibits an octahedral geometry, coordinated by four N atoms from the tris(2-py...

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Main Authors: Fan Yu, Bao Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811012001
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spelling doaj-7aa4bbef49e04ab1abf3ad75de66281d2020-11-24T21:28:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m566m56610.1107/S1600536811012001Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphateFan YuBao LiIn the title complex, [Co(CN)2(C18H18N4)]PF6, the CoIII atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The CoIII atom exhibits an octahedral geometry, coordinated by four N atoms from the tris(2-pyridylmethyl)amine ligand with an average Co—N distance of 1.953 (2) Å, and two cyanide C atoms with an average Co—C distance of 1.895 (2) Å. The crystal packing is stabilized by intermolecular C—H...N and C—H...F interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811012001
collection DOAJ
language English
format Article
sources DOAJ
author Fan Yu
Bao Li
spellingShingle Fan Yu
Bao Li
Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
Acta Crystallographica Section E
author_facet Fan Yu
Bao Li
author_sort Fan Yu
title Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
title_short Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
title_full Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
title_fullStr Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
title_full_unstemmed Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
title_sort dicyanido[tris(2-pyridylmethyl)amine]cobalt(iii) hexafluoridophosphate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-05-01
description In the title complex, [Co(CN)2(C18H18N4)]PF6, the CoIII atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The CoIII atom exhibits an octahedral geometry, coordinated by four N atoms from the tris(2-pyridylmethyl)amine ligand with an average Co—N distance of 1.953 (2) Å, and two cyanide C atoms with an average Co—C distance of 1.895 (2) Å. The crystal packing is stabilized by intermolecular C—H...N and C—H...F interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811012001
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AT baoli dicyanidotris2pyridylmethylaminecobaltiiihexafluoridophosphate
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