{N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II)
In the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811019945 |
| Summary: | In the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H...S hydrogen bonds, generating [100] chains. |
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| ISSN: | 1600-5368 |