Poly[μ2-aqua-[μ2-1,1′-(butane-1,4-diyl)diimidazole]bis(μ4-naphthalene-1,4-dicarboxylato)dimanganese(II)]

In the title compound, [Mn2(C12H6O4)2(C10H14N4)(H2O)]n or [Mn2(1,4-ndc)2(L)(H2O)]n, where 1,4-ndc is naphthalene-1,4-dicarboxylate and L is 1,1′-(butane-1,4-diyl)diimidazole, the coordination polyhedron around each MnII atom is distorted octahedral. The water molecule and the L ligand are...

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Bibliographic Details
Main Authors: Qun Xu, Wen-Zhi Zhang, Zhi-Qiang Chen
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808036787
Description
Summary:In the title compound, [Mn2(C12H6O4)2(C10H14N4)(H2O)]n or [Mn2(1,4-ndc)2(L)(H2O)]n, where 1,4-ndc is naphthalene-1,4-dicarboxylate and L is 1,1′-(butane-1,4-diyl)diimidazole, the coordination polyhedron around each MnII atom is distorted octahedral. The water molecule and the L ligand are situated across a twofold rotation axis. The MnII atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O—H...O hydrogen bonds are observed within the network.
ISSN:1600-5368