Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate

Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate

Reaction of cobalt(II) nitrate with potassium selenocyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)2(C4H4N2)4]·2C4H4N2, which is isotypic with its nickel(II) thiocyanate analogue. The Co2+ cations are coordinated by two N-bonded selenocyanate ligands and...

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Main Authors: Susanne Wöhlert, Mario Wriedt, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812027742
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spelling doaj-7c57be50a75b473a89f0e0f42f94cf5b2020-11-24T21:32:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m965m96510.1107/S1600536812027742Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvateSusanne WöhlertMario WriedtInke JessChristian NätherReaction of cobalt(II) nitrate with potassium selenocyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)2(C4H4N2)4]·2C4H4N2, which is isotypic with its nickel(II) thiocyanate analogue. The Co2+ cations are coordinated by two N-bonded selenocyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536812027742
collection DOAJ
language English
format Article
sources DOAJ
author Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
spellingShingle Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
Acta Crystallographica Section E
author_facet Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
author_sort Susanne Wöhlert
title Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
title_short Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
title_full Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
title_fullStr Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
title_full_unstemmed Tetrakis(pyridazine-κN)bis(selenocyanato-κN)cobalt(II) pyridazine disolvate
title_sort tetrakis(pyridazine-κn)bis(selenocyanato-κn)cobalt(ii) pyridazine disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description Reaction of cobalt(II) nitrate with potassium selenocyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)2(C4H4N2)4]·2C4H4N2, which is isotypic with its nickel(II) thiocyanate analogue. The Co2+ cations are coordinated by two N-bonded selenocyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812027742
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AT mariowriedt tetrakispyridazineamp954nbisselenocyanatoamp954ncobaltiipyridazinedisolvate
AT inkejess tetrakispyridazineamp954nbisselenocyanatoamp954ncobaltiipyridazinedisolvate
AT christiannamp228ther tetrakispyridazineamp954nbisselenocyanatoamp954ncobaltiipyridazinedisolvate
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