Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]

Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]

In the title compound, [Sm(C9I3O6)(C3H7NO)3]n, the SmIII atom is coordinated by nine O atoms, viz. six carboxylate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxylate (I3BTC) ligands and three O atoms from three N,N-dimethylformamide (DMF) molecules. Each I3BTC ligand bridges three SmIII at...

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Main Authors: Yanzhao Yang, Daopeng Sheng, Bin Yan
Format: Article
Language:English
Published: International Union of Crystallography 2013-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813003358
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spelling doaj-7c7524ee72574cab9809a5f1896e82b92020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693m149m14910.1107/S1600536813003358Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]Yanzhao YangDaopeng ShengBin YanIn the title compound, [Sm(C9I3O6)(C3H7NO)3]n, the SmIII atom is coordinated by nine O atoms, viz. six carboxylate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxylate (I3BTC) ligands and three O atoms from three N,N-dimethylformamide (DMF) molecules. Each I3BTC ligand bridges three SmIII atoms, generating a three-dimensional metal-organic framework structure. The asymmetric unit contains one SmIII ion and one I3BTC anion, both situated on a threefold axis, and one DMF molecule in a general position.http://scripts.iucr.org/cgi-bin/paper?S1600536813003358
collection DOAJ
language English
format Article
sources DOAJ
author Yanzhao Yang
Daopeng Sheng
Bin Yan
spellingShingle Yanzhao Yang
Daopeng Sheng
Bin Yan
Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
Acta Crystallographica Section E
author_facet Yanzhao Yang
Daopeng Sheng
Bin Yan
author_sort Yanzhao Yang
title Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
title_short Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
title_full Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
title_fullStr Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
title_full_unstemmed Poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(III)]
title_sort poly[tris(dimethylformamide)(μ3-2,4,6-triiodobenzene-1,3,5-tricarboxylato)samarium(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-03-01
description In the title compound, [Sm(C9I3O6)(C3H7NO)3]n, the SmIII atom is coordinated by nine O atoms, viz. six carboxylate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxylate (I3BTC) ligands and three O atoms from three N,N-dimethylformamide (DMF) molecules. Each I3BTC ligand bridges three SmIII atoms, generating a three-dimensional metal-organic framework structure. The asymmetric unit contains one SmIII ion and one I3BTC anion, both situated on a threefold axis, and one DMF molecule in a general position.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813003358
work_keys_str_mv AT yanzhaoyang polytrisdimethylformamide9563246triiodobenzene135tricarboxylatosamariumiii
AT daopengsheng polytrisdimethylformamide9563246triiodobenzene135tricarboxylatosamariumiii
AT binyan polytrisdimethylformamide9563246triiodobenzene135tricarboxylatosamariumiii
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