Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
The title compound, C39H37NO8, is a product of the Michael addition of the cyclic secondary amine subunit of aza-14-crown-4 ether to dimethyl acetylenedicarboxylate. The piperidinone ring exhibits a distorted chair conformation and the dimethyl acetylenedicarboxylate fragment has a cis configuration...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812015206 |
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doaj-7caa384a430546c59f4341d12d7bf7b12020-11-24T21:25:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1386o138710.1107/S1600536812015206Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioateVictor N. KhrustalevLe Tuan AnhSvetlana A. SoldatovaAnatoly T. SoldatenkovTruong Hong HieuThe title compound, C39H37NO8, is a product of the Michael addition of the cyclic secondary amine subunit of aza-14-crown-4 ether to dimethyl acetylenedicarboxylate. The piperidinone ring exhibits a distorted chair conformation and the dimethyl acetylenedicarboxylate fragment has a cis configuration with a dihedral angle of 56.61 (5)° between the two carboxylate groups. The crystal packing is stabilized by the weak C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812015206 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Victor N. Khrustalev Le Tuan Anh Svetlana A. Soldatova Anatoly T. Soldatenkov Truong Hong Hieu |
| spellingShingle |
Victor N. Khrustalev Le Tuan Anh Svetlana A. Soldatova Anatoly T. Soldatenkov Truong Hong Hieu Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate Acta Crystallographica Section E |
| author_facet |
Victor N. Khrustalev Le Tuan Anh Svetlana A. Soldatova Anatoly T. Soldatenkov Truong Hong Hieu |
| author_sort |
Victor N. Khrustalev |
| title |
Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| title_short |
Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| title_full |
Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| title_fullStr |
Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| title_full_unstemmed |
Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| title_sort |
dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-azatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-05-01 |
| description |
The title compound, C39H37NO8, is a product of the Michael addition of the cyclic secondary amine subunit of aza-14-crown-4 ether to dimethyl acetylenedicarboxylate. The piperidinone ring exhibits a distorted chair conformation and the dimethyl acetylenedicarboxylate fragment has a cis configuration with a dihedral angle of 56.61 (5)° between the two carboxylate groups. The crystal packing is stabilized by the weak C—H...O hydrogen bonds. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812015206 |
| work_keys_str_mv |
AT victornkhrustalev dimethyl223oxo2224diphenyl81114trioxa25azatetracyclo193102701520pentacosa24615201618hexaen25ylbut2enedioate AT letuananh dimethyl223oxo2224diphenyl81114trioxa25azatetracyclo193102701520pentacosa24615201618hexaen25ylbut2enedioate AT svetlanaasoldatova dimethyl223oxo2224diphenyl81114trioxa25azatetracyclo193102701520pentacosa24615201618hexaen25ylbut2enedioate AT anatolytsoldatenkov dimethyl223oxo2224diphenyl81114trioxa25azatetracyclo193102701520pentacosa24615201618hexaen25ylbut2enedioate AT truonghonghieu dimethyl223oxo2224diphenyl81114trioxa25azatetracyclo193102701520pentacosa24615201618hexaen25ylbut2enedioate |
| _version_ |
1725982972120662016 |