Control of asymmetric biaryl conformations with terpenol moieties: Syntheses, structures and energetics of new enantiopure C2-symmetric diols

Control of asymmetric biaryl conformations with terpenol moieties: Syntheses, structures and energetics of new enantiopure C2-symmetric diols

New enantiopure, C2-symmetric biphenyl-2,2′-diols based on (−)-menthone (BIMOL), (−)-verbenone (BIVOL) and (−)-carvone (BICOL and hydrogenated BIMEOL), are accessible via short, synthetic routes. All diols form intramolecular hydrogen bonds and hence can be employed as chelating ligands for catalyst...

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Bibliographic Details
Main Authors: Y. Alpagut, B. Goldfuss, J.-M. Neudörfl
Format: Article
Language:English
Published: Beilstein-Institut 2008-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chiral diols
hydrogen bonds
axial chirality
terpenes
Online Access:https://doi.org/10.3762/bjoc.4.25

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