Heterogeneous Asymmetric Oxidation Catalysis Using Hemophore HasApf. Application in the Chemoenzymatic Deracemization of sec-Alcohols with Sodium Borohydride
This study aims to demonstrate the coordination of oxygen regarding the hemophore HasApf expressed by Escherichia coli cells, which appears to create an unlikely oxygen-activating system in HasA due to the already-coordinated iron. In the asymmetric oxidation of rac-1-(6-methoxynaphthalen-2-yl)ethan...
Main Author: | Hiroyuki Nagaoka |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-03-01
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Series: | Catalysts |
Subjects: | |
Online Access: | http://www.mdpi.com/2073-4344/6/3/38 |
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