Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties

Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties

Noble metal nanoclusters are commonly protected by thiolate, phosphine, or alkynyl ligands. Here, the authors synthesize two homoleptic amido-protected silver clusters, whose structures interconvert easily with changes of solvent due to the coordination flexibility and diverse binding modes of the n...

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Main Authors: Shang-Fu Yuan, Zong-Jie Guan, Wen-Di Liu, Quan-Ming Wang
Format: Article
Language:English
Published: Nature Publishing Group 2019-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-11988-y
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spelling doaj-7db97729b27e4a96892ad95db76087562021-05-11T12:37:00ZengNature Publishing GroupNature Communications2041-17232019-09-011011710.1038/s41467-019-11988-ySolvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical propertiesShang-Fu Yuan0Zong-Jie Guan1Wen-Di Liu2Quan-Ming Wang3Department of Chemistry, Tsinghua UniversityDepartment of Chemistry, College of Chemistry and Chemical Engineering, Xiamen UniversityDepartment of Chemistry, Tsinghua UniversityDepartment of Chemistry, Tsinghua UniversityNoble metal nanoclusters are commonly protected by thiolate, phosphine, or alkynyl ligands. Here, the authors synthesize two homoleptic amido-protected silver clusters, whose structures interconvert easily with changes of solvent due to the coordination flexibility and diverse binding modes of the nitrogen-donor ligands.https://doi.org/10.1038/s41467-019-11988-y
collection DOAJ
language English
format Article
sources DOAJ
author Shang-Fu Yuan
Zong-Jie Guan
Wen-Di Liu
Quan-Ming Wang
spellingShingle Shang-Fu Yuan
Zong-Jie Guan
Wen-Di Liu
Quan-Ming Wang
Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
Nature Communications
author_facet Shang-Fu Yuan
Zong-Jie Guan
Wen-Di Liu
Quan-Ming Wang
author_sort Shang-Fu Yuan
title Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
title_short Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
title_full Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
title_fullStr Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
title_full_unstemmed Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
title_sort solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-09-01
description Noble metal nanoclusters are commonly protected by thiolate, phosphine, or alkynyl ligands. Here, the authors synthesize two homoleptic amido-protected silver clusters, whose structures interconvert easily with changes of solvent due to the coordination flexibility and diverse binding modes of the nitrogen-donor ligands.
url https://doi.org/10.1038/s41467-019-11988-y
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AT zongjieguan solventtriggeredreversibleinterconversionofallnitrogendonorprotectedsilvernanoclustersandtheirresponsiveopticalproperties
AT wendiliu solventtriggeredreversibleinterconversionofallnitrogendonorprotectedsilvernanoclustersandtheirresponsiveopticalproperties
AT quanmingwang solventtriggeredreversibleinterconversionofallnitrogendonorprotectedsilvernanoclustersandtheirresponsiveopticalproperties
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