DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions

3,5-disubstituted-2,6-dicyanoaniline derivatives have been synthesized via the reaction of aryl methylene- and 1-arylethylidenemalonodinitriles using 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) as a  novel and highly efficient catalyst under conventional as well as microwave conditions. Use of non-haz...

Full description

Bibliographic Details
Main Authors: Balwant S. Keshwal, Deepika Rajguru, Aman D. Acharya
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2016-02-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_18805_ddb931a5dd740c8031990ef550dee3d1.pdf
id doaj-7ee7f7bb59c14b4ab300fffd7ae58006
record_format Article
spelling doaj-7ee7f7bb59c14b4ab300fffd7ae580062020-11-25T03:19:02ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862016-02-01351374218805DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave ConditionsBalwant S. Keshwal0Deepika Rajguru1Aman D. Acharya2School of Studies in Chemistry, Vikram University, Ujjain, Madhya Pradesh, 456010, INDIASchool of Studies in Chemistry, Vikram University, Ujjain, Madhya Pradesh, 456010, INDIADepartment of Physics, Lovely Professional University, Phagwara, Punjab, 144411, INDIA3,5-disubstituted-2,6-dicyanoaniline derivatives have been synthesized via the reaction of aryl methylene- and 1-arylethylidenemalonodinitriles using 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) as a  novel and highly efficient catalyst under conventional as well as microwave conditions. Use of non-hazardous, inexpensive and readily available base catalyst, convenient procedure, short reaction time and improved product yields are some added advantages of the present protocol.http://www.ijcce.ac.ir/article_18805_ddb931a5dd740c8031990ef550dee3d1.pdf1,8-diazabicyclo[5.4.0]undec-7-ene (dbu)3,5-disubstituted-2,6-dicyanoanilinesmicrowavesynthesis
collection DOAJ
language English
format Article
sources DOAJ
author Balwant S. Keshwal
Deepika Rajguru
Aman D. Acharya
spellingShingle Balwant S. Keshwal
Deepika Rajguru
Aman D. Acharya
DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
Iranian Journal of Chemistry & Chemical Engineering
1,8-diazabicyclo[5.4.0]undec-7-ene (dbu)
3,5-disubstituted-2,6-dicyanoanilines
microwave
synthesis
author_facet Balwant S. Keshwal
Deepika Rajguru
Aman D. Acharya
author_sort Balwant S. Keshwal
title DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
title_short DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
title_full DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
title_fullStr DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
title_full_unstemmed DBU As A Novel and Highly Efficient Catalyst for The Synthesis of 3,5-Disubstituted-2,6-dicyanoanilines Under Conventional and Microwave Conditions
title_sort dbu as a novel and highly efficient catalyst for the synthesis of 3,5-disubstituted-2,6-dicyanoanilines under conventional and microwave conditions
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2016-02-01
description 3,5-disubstituted-2,6-dicyanoaniline derivatives have been synthesized via the reaction of aryl methylene- and 1-arylethylidenemalonodinitriles using 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) as a  novel and highly efficient catalyst under conventional as well as microwave conditions. Use of non-hazardous, inexpensive and readily available base catalyst, convenient procedure, short reaction time and improved product yields are some added advantages of the present protocol.
topic 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu)
3,5-disubstituted-2,6-dicyanoanilines
microwave
synthesis
url http://www.ijcce.ac.ir/article_18805_ddb931a5dd740c8031990ef550dee3d1.pdf
work_keys_str_mv AT balwantskeshwal dbuasanovelandhighlyefficientcatalystforthesynthesisof35disubstituted26dicyanoanilinesunderconventionalandmicrowaveconditions
AT deepikarajguru dbuasanovelandhighlyefficientcatalystforthesynthesisof35disubstituted26dicyanoanilinesunderconventionalandmicrowaveconditions
AT amandacharya dbuasanovelandhighlyefficientcatalystforthesynthesisof35disubstituted26dicyanoanilinesunderconventionalandmicrowaveconditions
_version_ 1724624143555493888