Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric
In this work, acidity constants protonated form of 4.4'-bis astilbene-2,2'-disulfonic-disodium salts (TRIAZ) have been determined spectrophotometrically and spectrofluorimetrically at 25◦C and ionic strength of 0.1M KNO3. A program based on MCR-ALS applied for determination of acidity cons...
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Growing Science
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doaj-7ee8fc2f3eb64657ad237c71b8350fa22020-11-24T21:05:27ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2014-03-013211512410.5267/j.ccl.2013.11.002Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and SpectrofluorimetricAli Yeganeh FaalTavakol Heidary ShayesteMaryam BordbarBahare JamalyanIn this work, acidity constants protonated form of 4.4'-bis astilbene-2,2'-disulfonic-disodium salts (TRIAZ) have been determined spectrophotometrically and spectrofluorimetrically at 25◦C and ionic strength of 0.1M KNO3. A program based on MCR-ALS applied for determination of acidity constants. The results show that the peak values of dye are influenced by the presence of anionic, cationic, and nonionic surfactants. The effects of sodium dodecyl sulfate (SDS), Triton X-100 (TX-100) and cetyl trimethyl ammonium bromide (CTAB) as a surface-active agent on the acidic and basic forms, and the spectral properties of dye were studied. Also, we determined the critical micelle concentration (CMC) for these surfactants by spectrophotometric and spectrofluorimetric triazine dye probes. In addition, by using of evolving factor analysis (EFA) and multivariate curve resolution alternative least squares (MCR-ALS) methods, acidity constants were acquired.http://www.growingscience.com/ccl/Vol3/ccl_2013_28.pdfTriazineAcidity constantSurfactantSpectrophotometricSpectrofluorimetric |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ali Yeganeh Faal Tavakol Heidary Shayeste Maryam Bordbar Bahare Jamalyan |
spellingShingle |
Ali Yeganeh Faal Tavakol Heidary Shayeste Maryam Bordbar Bahare Jamalyan Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric Current Chemistry Letters Triazine Acidity constant Surfactant Spectrophotometric Spectrofluorimetric |
author_facet |
Ali Yeganeh Faal Tavakol Heidary Shayeste Maryam Bordbar Bahare Jamalyan |
author_sort |
Ali Yeganeh Faal |
title |
Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric |
title_short |
Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric |
title_full |
Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric |
title_fullStr |
Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric |
title_full_unstemmed |
Acidity Constants Determination of Triazine Dye Derivative in the presence of some Surfactants by Multiwavelength Spectrophotometric and Spectrofluorimetric |
title_sort |
acidity constants determination of triazine dye derivative in the presence of some surfactants by multiwavelength spectrophotometric and spectrofluorimetric |
publisher |
Growing Science |
series |
Current Chemistry Letters |
issn |
1927-7296 1927-730X |
publishDate |
2014-03-01 |
description |
In this work, acidity constants protonated form of 4.4'-bis astilbene-2,2'-disulfonic-disodium salts (TRIAZ) have been determined spectrophotometrically and spectrofluorimetrically at 25◦C and ionic strength of 0.1M KNO3. A program based on MCR-ALS applied for determination of acidity constants. The results show that the peak values of dye are influenced by the presence of anionic, cationic, and nonionic surfactants. The effects of sodium dodecyl sulfate (SDS), Triton X-100 (TX-100) and cetyl trimethyl ammonium bromide (CTAB) as a surface-active agent on the acidic and basic forms, and the spectral properties of dye were studied. Also, we determined the critical micelle concentration (CMC) for these surfactants by spectrophotometric and spectrofluorimetric triazine dye probes. In addition, by using of evolving factor analysis (EFA) and multivariate curve resolution alternative least squares (MCR-ALS) methods, acidity constants were acquired. |
topic |
Triazine Acidity constant Surfactant Spectrophotometric Spectrofluorimetric |
url |
http://www.growingscience.com/ccl/Vol3/ccl_2013_28.pdf |
work_keys_str_mv |
AT aliyeganehfaal acidityconstantsdeterminationoftriazinedyederivativeinthepresenceofsomesurfactantsbymultiwavelengthspectrophotometricandspectrofluorimetric AT tavakolheidaryshayeste acidityconstantsdeterminationoftriazinedyederivativeinthepresenceofsomesurfactantsbymultiwavelengthspectrophotometricandspectrofluorimetric AT maryambordbar acidityconstantsdeterminationoftriazinedyederivativeinthepresenceofsomesurfactantsbymultiwavelengthspectrophotometricandspectrofluorimetric AT baharejamalyan acidityconstantsdeterminationoftriazinedyederivativeinthepresenceofsomesurfactantsbymultiwavelengthspectrophotometricandspectrofluorimetric |
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