Crystal structure of chlorido{tris[2-(isopropylsulfanyl)phenyl]phosphane-κ4P,S,S′,S′′}nickel(II) trifluoromethanesulfonate

Crystal structure of chlorido{tris[2-(isopropylsulfanyl)phenyl]phosphane-κ4P,S,S′,S′′}nickel(II) trifluoromethanesulfonate

The complex cation of the title compound, [NiCl{P(C6H4-2-S-i-Pr)3}](CF3SO3), has a slightly distorted trigonal–bipyramidal coordination geometry in which three S atoms are located in the equatorial plane, and one P and one Cl atom in the apical positions. In the cation, there are two intramolecular...

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Bibliographic Details
Main Authors: Nobuhiro Takeda, Rin Oma, Masafumi Unno
Format: Article
Language:English
Published: International Union of Crystallography 2019-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
nickel
five-coordinate
tripodal tetradentate ligand
phosphine
thioether
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019002068

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