Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite
Abstract Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the in-situ adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first...
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doaj-7f8fbdd55b094183b6b4f9e3481bde392020-12-08T04:53:31ZengNature Publishing GroupScientific Reports2045-23222018-10-018111310.1038/s41598-018-34144-wInvestigation on the adsorption of phosphorus in all fractions from sediment by modified maifaniteZisen Liu0Yi Zhang1Fan Han2Pan Yan3Biyun Liu4Qiaohong Zhou5Fenli Min6Feng He7Zhenbin Wu8State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesSchool of Resources and Environmental Engineering, Wuhan University of TechnologyState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesState Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of SciencesAbstract Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the in-situ adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H2SO4 and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the in-situ adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment.https://doi.org/10.1038/s41598-018-34144-wAdsorption RateFourier Transform Infrared (FTIR)Adsorption CapacityModification TreatmentCombined Modifications |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Zisen Liu Yi Zhang Fan Han Pan Yan Biyun Liu Qiaohong Zhou Fenli Min Feng He Zhenbin Wu |
spellingShingle |
Zisen Liu Yi Zhang Fan Han Pan Yan Biyun Liu Qiaohong Zhou Fenli Min Feng He Zhenbin Wu Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite Scientific Reports Adsorption Rate Fourier Transform Infrared (FTIR) Adsorption Capacity Modification Treatment Combined Modifications |
author_facet |
Zisen Liu Yi Zhang Fan Han Pan Yan Biyun Liu Qiaohong Zhou Fenli Min Feng He Zhenbin Wu |
author_sort |
Zisen Liu |
title |
Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
title_short |
Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
title_full |
Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
title_fullStr |
Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
title_full_unstemmed |
Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
title_sort |
investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
publisher |
Nature Publishing Group |
series |
Scientific Reports |
issn |
2045-2322 |
publishDate |
2018-10-01 |
description |
Abstract Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the in-situ adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H2SO4 and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the in-situ adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment. |
topic |
Adsorption Rate Fourier Transform Infrared (FTIR) Adsorption Capacity Modification Treatment Combined Modifications |
url |
https://doi.org/10.1038/s41598-018-34144-w |
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