Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate
In the title compound, [CuCl(C10H8N2)2]2[Bi2Cl4(C7H3NO4)2(H2O)2]·5H2O, the dianion [Bi2Cl4(C7H3NO4)2(H2O)2]2− is located about an inversion center. The CuII atom of the cation is coordinated by four N atoms of the two chelating 2,2′-bypyridine ligands and one...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-12-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811045259 |
id |
doaj-7faf230ef07b43a9803a623ca2f4a881 |
---|---|
record_format |
Article |
spelling |
doaj-7faf230ef07b43a9803a623ca2f4a8812020-11-25T01:00:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1651m165110.1107/S1600536811045259Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrateHong-Wei WangWan-Lan LiuYu-Quan FengIn the title compound, [CuCl(C10H8N2)2]2[Bi2Cl4(C7H3NO4)2(H2O)2]·5H2O, the dianion [Bi2Cl4(C7H3NO4)2(H2O)2]2− is located about an inversion center. The CuII atom of the cation is coordinated by four N atoms of the two chelating 2,2′-bypyridine ligands and one Cl− ion, completing a distorted trigonal–bipyramidal coordination environment. In the anion, each BiIII atom is seven-coordinate and is bonded to a tridentate pyridine-2,6-dicarboxylate ligand, a water molecule, two chloride ions and a bridging carboxylate O atom of another carboxylate ligand. The coordination geometry of BiIII is distorted pentagonal–bipyramidal with the Cl− ions located in axial positions. The structure of the dianion is additionally stabilized by an intramolecular O—H...O hydrogen bond between the coordinated water molecule and carboxylate O atom. In the crystal, O—H...O hydrogen bonds occur . The H atoms of the solvent water molecules could not be located.http://scripts.iucr.org/cgi-bin/paper?S1600536811045259 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hong-Wei Wang Wan-Lan Liu Yu-Quan Feng |
spellingShingle |
Hong-Wei Wang Wan-Lan Liu Yu-Quan Feng Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate Acta Crystallographica Section E |
author_facet |
Hong-Wei Wang Wan-Lan Liu Yu-Quan Feng |
author_sort |
Hong-Wei Wang |
title |
Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate |
title_short |
Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate |
title_full |
Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate |
title_fullStr |
Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate |
title_full_unstemmed |
Bis[bis(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] bis(μ-2,6-pyridinedicarboxylato)-κ4O2,N,O6:O6;κ4O2:O2,N,O6-bis[aquadichloridobismuthate(III)] pentahydrate |
title_sort |
bis[bis(2,2′-bipyridine-κ2n,n′)chloridocopper(ii)] bis(μ-2,6-pyridinedicarboxylato)-κ4o2,n,o6:o6;κ4o2:o2,n,o6-bis[aquadichloridobismuthate(iii)] pentahydrate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-12-01 |
description |
In the title compound, [CuCl(C10H8N2)2]2[Bi2Cl4(C7H3NO4)2(H2O)2]·5H2O, the dianion [Bi2Cl4(C7H3NO4)2(H2O)2]2− is located about an inversion center. The CuII atom of the cation is coordinated by four N atoms of the two chelating 2,2′-bypyridine ligands and one Cl− ion, completing a distorted trigonal–bipyramidal coordination environment. In the anion, each BiIII atom is seven-coordinate and is bonded to a tridentate pyridine-2,6-dicarboxylate ligand, a water molecule, two chloride ions and a bridging carboxylate O atom of another carboxylate ligand. The coordination geometry of BiIII is distorted pentagonal–bipyramidal with the Cl− ions located in axial positions. The structure of the dianion is additionally stabilized by an intramolecular O—H...O hydrogen bond between the coordinated water molecule and carboxylate O atom. In the crystal, O—H...O hydrogen bonds occur . The H atoms of the solvent water molecules could not be located. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811045259 |
work_keys_str_mv |
AT hongweiwang bisbis22amp8242bipyridineamp9542nnamp8242chloridocopperiibisamp95626pyridinedicarboxylatoamp9544o2no6o6amp9544o2o2no6bisaquadichloridobismuthateiiipentahydrate AT wanlanliu bisbis22amp8242bipyridineamp9542nnamp8242chloridocopperiibisamp95626pyridinedicarboxylatoamp9544o2no6o6amp9544o2o2no6bisaquadichloridobismuthateiiipentahydrate AT yuquanfeng bisbis22amp8242bipyridineamp9542nnamp8242chloridocopperiibisamp95626pyridinedicarboxylatoamp9544o2no6o6amp9544o2o2no6bisaquadichloridobismuthateiiipentahydrate |
_version_ |
1725214244934254592 |